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Oxidation of dimethyl sulfoxide with hydrogen peroxide in the presence of potassium hydroxide

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Abstract

Kinetic relationships in oxidation of DMSO to dimethyl sulfone with hydrogen peroxide in the presence of potassium hydroxide were studied. Kinetic parameters of the process were calculated. It was established that the reaction proceeded through the intermediate formation of potassium hydroperoxide.

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Authors and Affiliations

  1. Fed’kovich Chernovtsy National University, ul. Kotsyubinskogo 2, Chernovtsy, 58012, Ukraine

    A. F. Choban, I. R. Yurchuk & A. S. Lyavinets

Authors
  1. A. F. Choban
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  2. I. R. Yurchuk
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  3. A. S. Lyavinets
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Correspondence to A. S. Lyavinets.

Additional information

Original Russian Text © A.F. Choban, I.R. Yurchuk, A.S. Lyavinets, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 11, pp. 1838–1841.

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Choban, A.F., Yurchuk, I.R. & Lyavinets, A.S. Oxidation of dimethyl sulfoxide with hydrogen peroxide in the presence of potassium hydroxide. Russ J Gen Chem 78, 2071–2074 (2008). https://doi.org/10.1134/S1070363208110157

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  • DOI: https://doi.org/10.1134/S1070363208110157

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