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Synthesis, spectral, thermal and biological studies of Co(III) and binuclear Ni(II) complexes with a novel amine-imine-oxime ligand

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Abstract

Two different metal complexes of [Co(HL)(L)(Ac)2]·4H2O (I) and [Ni2(L)2(Ac)2]·4H2O (II), have been synthesized with newly prepared amine-imine-oxime ligand [HL = 3-(4′-aminobiphenyl-4-ylimino)-butan-2-one oxime, Ac = CH3COO−]. This ligand HL was prepared by the condensation of diacetylmonoxime with benzidine. The structure of the ligand and complexes have been proposed by elemental analyses, IR, 1H, and 13C NMR, electronic spectra, magnetic susceptibility measurements, mass spectra, molar conductivity and thermo gravimetric analysis. The molar conductance measurements of the complexes in DMF solution correspond to non electrolytic nature for the complexes. Octahedral and tetrahedral geometries have been determined to the complexes of Co(III) and binuclear Ni(II) respectively. The ligand and its metal complexes were tested in vitro for their biological effects. Their activities against two gram-positive (Bacillus subtilis and Staphylococcus aureus) and one fungal specie (Candida albicans) were found. They were inactive against tested gram negative bacteria.

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Authors and Affiliations

  1. Faculty of Science and Arts, Departmenot tested of Chemistry, Dumlupınar University, Kütahya, 43100, Turkey

    Muharrem Kaya, Cengiz Yenikaya & Alper Tolga Colak

  2. Department of Biology, Faculty of Arts and Sciences, Dumlupinar University, Kütahya, Turkey

    Ferdag Colak

Authors
  1. Muharrem Kaya
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  2. Cengiz Yenikaya
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  3. Alper Tolga Colak
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  4. Ferdag Colak
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Correspondence to Muharrem Kaya.

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The text was submitted by authors in English.

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Kaya, M., Yenikaya, C., Colak, A.T. et al. Synthesis, spectral, thermal and biological studies of Co(III) and binuclear Ni(II) complexes with a novel amine-imine-oxime ligand. Russ J Gen Chem 78, 1808–1815 (2008). https://doi.org/10.1134/S1070363208090260

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  • DOI: https://doi.org/10.1134/S1070363208090260

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