Skip to main content
SpringerLink
Log in

Development of a one-stage synthesis of 2,6-di-tert-4-ethylbutylphenol from 2,6-di-tert-butylphenol

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Investigation of the catalyzed reaction of 2,6-di-tert-butylphenol with ethanol, ethylene glycol, oligomeric glycols, and paraldehyde in a strongly basic medium permitted to develop a technologically suitable procedure for manufacture of 2,6-di-tert-4-ethyl-butylphenol, used in the synthesis of Antioxidant-425.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Oberright, E.A. and Leonardi, S.J., FR Patent 1399146, 1965, Chem. Abstr., 1966, vol. 64, no. 1881.

  2. Paxeus, N., Water Res., 1996, vol. 30, no. 5, p. 1115.

    Article  CAS  Google Scholar 

  3. Wollensak, J.C., US Patent 3919333, 1975; Chem. Abstr., 1976, vol 84, no. 45611b.

  4. Shim, Yeongwoo, Lim, Seonghoan, Lee, Choohjae, and Ahn, Hancheol, Int. Patent 2006 78.123; Chem. Abstr., 2006, vol. 145, no. 146195.

  5. Zenkov, N.K., Kandalintseva, N.V., Lankin, V.Z., Men’shikova, E.B., and Prosenko, A.E., Phenol’nye bioantioksidanty (Phenolic Bioantioxidants), Novosibirsk: Sib. Otd. Ross. Akad. Med. Nauk, 2003, p. 33.

    Google Scholar 

  6. Chem. Eng. News, 1978, vol. 56, no. 13, p. 38.

  7. Takahashi, N., Yamashita, F., Mesaki, J., and Nishimura, A., JP Patent 01.113.052; Chem. Abstr., 1990, vol. 112, no. 83884w.

  8. Cook, C.D. and Norcross, B.E., J. Am. Chem. Soc., 1959, vol. 81, p. 1176.

    Article  CAS  Google Scholar 

  9. He, Yi., Sun, Ting, and Yae, Mel, Jinngxi Huagong, 2004, vol. 21, p. 149; Chem. Abstr., 2006, vol. 143, no. 306985.

    CAS  Google Scholar 

  10. Isaguluants, V.I., Tishkova, V.I., Favorskaya, I.A., and Oganisyan, R.O., Tr. Mosk. Neft. Inst. im. I.M. Gubkina, 1958, no. 23, p. 42.

  11. Afanas’ev, N.D., Gushanskaya, P.G., Dobkin, N.E., and Sycheva, A.F., Prisadki k maslam. Trudt 2 Vsosoyuznogo soveshaniya (Oil Additives, Proc. Second All-Union Conf.), 1966, book 1, p. 129.

  12. Yamahara, Takeshi, Takano, Tetsuo, Tamura, Mitsuhisa, and Yochira, Hiroshi, DE Patent 2619300, 1976; Chem. Abstr., 1977, vol. 86, no. 72194.

  13. Liakumovich, A.G., Tolstikov, G.A., Yur’ev, V.P., Gurvich, Ya.A., Gershanov, F.B., Murtazina, Z.A., USSR Inventor’s Certificate no. 368220, 1973; Byull. Izobret., 1973, no. 9.

  14. Volod’kin, A.A., Ershov, V.V., and Portnykh, N.V., Izv. Akad. Nauk SSSR, Ser. Khim., 1967, no. 2, p. 409.

  15. Krysin, A.P., Pokrovskii, L.M., and Shakirov, M.M., Zh. Org. Khim., 2000, vol. 36, no. 1, p. 79.

    Google Scholar 

  16. Iwahara, Misahiro, Eur. Patent 2254228, 1988; Chem. Abstr., 1988, vol. 109, no. 8398a.

  17. Douglas, G., Norton, D.G., and Morris, R.C., US Patent 2841623, 1958; Chem. Abstr., 1958, vol. 52, no. P1718i.

  18. Gurvich, Ya.A., Kumok, S.T., Lopatin, V.V., and Starikova, O.F., Fenol’nye stabilizatory. Sostoyanie i perspektivy (Phenolic Stabilizers. Modern State and Horizons), Moasocw: TsNIITEheftekhim, 1990, no. 5, p. 34.

    Google Scholar 

  19. Wu, J., Polce, M.J., and Wesdemiotis, Ch., J. Am. Chem. Soc., 2000, vol. 122, no. 51, p. 12786.

    Article  CAS  Google Scholar 

  20. Kulikov, S.M., Kozhevnikov, I.V., Fomina, M.N., and Krysin, A.P., Izv. Akad. Nauk SSSR, Ser. Khim., 1987, no. 4, p. 752.

  21. Kulikov, S.M., Krysin, A.P., Kobrin, V.S., Kozhevnikov I.V., and Aksenov, V.V., USSR Inventor’s Certificate no. 1192306, 1984; Byull. Izobret., 1987, no. 5.

Download references

Author information

Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Akad. Lavrent’eva 9, Novosibirsk, 630090, Russia

    A. P. Krysin & L. M. Pokrovskii

Authors
  1. A. P. Krysin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. M. Pokrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. P. Krysin.

Additional information

Original Russian Text © A.P. Krysin, L.M. Pokrovskii, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 9, pp. 1496–1501.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krysin, A.P., Pokrovskii, L.M. Development of a one-stage synthesis of 2,6-di-tert-4-ethylbutylphenol from 2,6-di-tert-butylphenol. Russ J Gen Chem 78, 1728–1733 (2008). https://doi.org/10.1134/S1070363208090144

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363208090144

Keywords

Search

Navigation