Skip to main content
SpringerLink
Log in

Synthesis of polymolybdenophenylsiloxane

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Polymolybdenophenylsiloxane containing Mo(V) atoms and preserving the Si : Mo ratio equal to that in the starting mixture was prepared by the reaction of molybdenum(V) oxychloride dimethyl sulfoxide crystal solvate with sodium polyphenylsiliconate in the presence of dimethyl sulfoxide. The influence of the reaction conditions on the nature and yields of products was examined. Experiments on thermal oxidative degradation of polymolybdenophenylsiloxane showed that it is more stable compared to the previously studied polymetalloorganosiloxanes containing various d elements with the stoichiometric Si : metal ratio.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Voronkov, M.G., Maletina, E.A., and Roman, V.K., Geteropolisiloksany (Heteropolysiloxanes), Novosibirsk: Nauka, 1984.

    Google Scholar 

  2. Voronkov, M.G., Alikovskii, A.V., and Zolotar’, G.Ya., Dokl. Akad. Nauk SSSR, 1985, vol. 281, no. 4, p. 858.

    CAS  Google Scholar 

  3. Cotton, F.A. and Wilkinson, G., Advanced Inorganic Chemistry. A Comprehensive Text, New York: Interscience, 1962.

    Google Scholar 

  4. Voronkov, M.G., Mileshkevich, V.P., and Yuzhelevskii, Yu.A., Siloksanovaya svyaz’ (Siloxane Bond), Novosibirsk: Nauka, 1976.

    Google Scholar 

  5. Remy, H., Lehrbuch der anorganischen Chemie, Leipzig: Geest und Portig, 1961.

    Google Scholar 

  6. Alikovskii, A.V., Zolotar’, G.Ya., Bessonova, V.I., and Krasitskaya, S.G., in Materialy IV Mezhdunarodnogo simpoziuma “Peterburgskie vstrechi” (Proc. IV Int. Symp. “Petersburg Meetings”), St. Petersburg, 2002, p. 346.

Download references

Author information

Authors and Affiliations

  1. Far-Eastern State University, ul. Sukhanova 8, Vladivostok, 690950, Russia

    A. V. Alikovskii, S. G. Krasitskaya & M. I. Balanov

Authors
  1. A. V. Alikovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. G. Krasitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. I. Balanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. G. Krasitskaya.

Additional information

Original Russian Text © A.V. Alikovskii, S.G. Krasitskaya, M.I. Balanov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 4, pp. 600–603.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alikovskii, A.V., Krasitskaya, S.G. & Balanov, M.I. Synthesis of polymolybdenophenylsiloxane. Russ J Gen Chem 78, 581–584 (2008). https://doi.org/10.1134/S1070363208040117

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363208040117

Keywords

Search

Navigation