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Synthesis, structure, and properties of new phosphorus Schiff bases

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Abstract

A series of new Schiff bases has been synthesized on the basis of (2-aminophenyl)triphenyl-phosphonium chloride and substituted salicylaldehydes. The structure of the prepared compounds has been established by means of IR, UV, and 1H NMR spectroscopy, as well as DFT B3LYP/6-31G(d,p) quantum-chemical simulation. The possible tautomerism and certain properties of the azomethines, including complex formation, have been studied.

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Authors and Affiliations

  1. Southern Federal University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    L. D. Popov, S. A. Borodkin, I. N. Shcherbakov, Yu. N. Tkachenko & V. A. Kogan

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  1. L. D. Popov
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  2. S. A. Borodkin
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  3. I. N. Shcherbakov
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  4. Yu. N. Tkachenko
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  5. V. A. Kogan
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Correspondence to S. A. Borodkin.

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Original Russian Text © L.D. Popov, S.A. Borodkin, I.N. Shcherbakov, Yu.N. Tkachenko, V.A. Kogan, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 4, pp. 586–593.

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Popov, L.D., Borodkin, S.A., Shcherbakov, I.N. et al. Synthesis, structure, and properties of new phosphorus Schiff bases. Russ J Gen Chem 78, 567–574 (2008). https://doi.org/10.1134/S1070363208040099

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  • DOI: https://doi.org/10.1134/S1070363208040099

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