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Structure, magnetic, and electric properties of bismuth niobates doped with d-Elements: VI. Magnetic behavior of Bi3Nb3−3x Ni3x O15−δ solid solutions

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Abstract

Magnetic susceptibility of nickel-containing solid solutions with layered perovskite-like structure of bismuth niobate, Bi5Nb3O15, was studied. High-spin nickel atoms, Ni(III), were present at low concentrations of the solid solutions. The formation of exchange-bonded aggregates (dimers) of nickel(II) atoms with antiferromagnetic type of exchange was found in the solid solutions. The parameters of exchange interactions in the dimer clusters and the distribution of monomers and dimers of nickel atoms were calculated as a function of the solid solution concentration.

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Authors and Affiliations

  1. Syktyvkar State University, Syktyvkar, Russia

    N. A. Zhuk & I. V. Piir

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    N. V. Chezhina

Authors
  1. N. A. Zhuk
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  2. I. V. Piir
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  3. N. V. Chezhina
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Additional information

Original Russian Text © N.A. Zhuk, I.V. Piir, N.V. Chezhina, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 3, pp. 393–399.

For communication V, see [1].

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Zhuk, N.A., Piir, I.V. & Chezhina, N.V. Structure, magnetic, and electric properties of bismuth niobates doped with d-Elements: VI. Magnetic behavior of Bi3Nb3−3x Ni3x O15−δ solid solutions. Russ J Gen Chem 78, 376–382 (2008). https://doi.org/10.1134/S1070363208030079

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  • DOI: https://doi.org/10.1134/S1070363208030079

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