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Design strategy of enediynes and enyne-allenes

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Abstract

The review summarizes synthetic approaches to enediynes and enyne-allenes that are responsible for a Bergman and Myers-Saito cycloaromatizations resulting in the formation of benzene, β-substituted naphthalene, and acene derivatives. Cycloaromatization paths leading to fulvene and indene systems in the presence of radical and ionic initiators, as well as of metal catalysts, are discussed. Practical importance of the syntheses is noted.

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    I. A. Maretina

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Original Russian Text © I.A. Maretina, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 2, pp. 244–278.

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Maretina, I.A. Design strategy of enediynes and enyne-allenes. Russ J Gen Chem 78, 223–257 (2008). https://doi.org/10.1134/S1070363208020126

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