Abstract
The molar volumes of polyphenylmethanes, polyarylethanes, polyaryl compounds based on pyridinium cations, polyarylethylenes, and also diaryl and hetaryl ketones in various solvents were determined. Additive analysis of the molar volumes of these compounds showed that the aryl rings in their molecules are acoplanar to the bridging groups in which these rings can rotate about single bonds. The most probable is the conrotatory model of mutual orientation of the aromatic rings relative to each other. This orientation is similar to that found previously in solutions of such molecules as diphenylmethane, benzophenone, and some others, according to data of various physical methods. The possibility of substantial simplification of methods for determining the dipole moments, Cotton-Mouton constants, and Kerr constants for the compounds under consideration was demonstrated.
Similar content being viewed by others
References
Bulgarevich, S.B., Burdastykh, T.V., and Boiko, M.V., Zh. Obshch. Khim., 2007, vol. 77, no. 7, p. 1162.
Aroney, M.J., Le Fevre, R.J.W., Ritchie, G.L.D., and Singh, A.N., J. Chem. Soc., 1965, no. 11, p. 5810.
Calderbank, K.E., Le Fevre, R.J.W., and Pierens, R.K., J. Chem. Soc. B, 1970, no. 6, p. 1115.
Kemp, M.L. and Le Fevre, R.J.W., J. Chem. Soc., 1965, no. 12, p. 7094.
Bulgarevich, S.B., Bren, D.V., Movshovich, D.Y., Finocchiaro, P., and Failla, S., J. Mol. Struct., 1994, vol. 317, p. 147.
Bulgarevich, S.B., Bren, D.V., Movshovich, D.Y., Finocchiaro, P., and Failla, S., J. Mol. Struct., 1994, vol. 318, p. 179.
Bulgarevich, S.B., Movshovich, D.Y., Ivanova, N.A., Gruntfest, M.G., Finocchiaro, P., and Failla, S., J. Mol. Struct., 1994, vol. 328, p. 259.
Bramley, R. and Le Fevre, R.J.W., J. Chem. Soc., 1962, no. 1, p. 56.
Gore, P.H., Hoskins, J.A., Le Fevre, R.J.W., Radom, L., and Ritchie, G.L.D., J. Chem. Soc. B, 1967, no. 8, p. 741.
Cheng, C.L., Le Fevre, R.J.W., Ritchie, G.L.D., Gore, P.H., and Yusuf, M., J. Chem. Soc. B, 1971, no. 8, p. 1579.
Gore, P.H., John, I.G., Pierens, R.K., and Ritchie, G.L.D., Aust. J. Chem., 1980, vol. 33, no. 12, p. 2597.
Aroney, M.J., Hoskins, G.M., and Le Fevre, R.J.W., J. Chem. Soc. B, 1969, no. 8, p. 980.
Bulgarevich, S.B., Burdastykh, T.V., and Tishchenko, L.G., Zh. Obshch. Khim., 2006, vol. 76, no. 6, p. 999.
Bulgarevich, S.B., Burdastykh, T.V., Tishchenko, L.G., and Kosheleva, I.V., Zh. Obshch. Khim., 2005, vol. 75, no. 11, p. 1866.
Bulgarevich, S.B., Burdastykh, T.V., and Selezneva, E.S., Zh. Obshch. Khim., 2007, vol. 77, no. 4, p. 637.
Gonikberg, M.G., Khimicheskoe ravnovesie i skorosti reaktsii pri vysokikh davleniyakh (Chemical Equilibrium and Reaction Rates at High Pressures), Moscow: Khimiya, 1969.
Le Fevre, C.G. and Le Fevre, R.J.W., J. Chem. Soc., 1953, no. 12, p. 4041.
Aroney, M.J., Le Fevre, R.J.W., and Saxby, J., J. Chem. Soc., 1962, no. 8, p. 2886.
Le Fevre, C.G. and Le Fevre, R.J.W., J. Chem. Soc., 1954, no. 5, p. 1577.
Svoistva organicheskikh soedinenii (Properties of Organic Compounds), Potekhin, A.A., Ed., Leningrad: Khimiya, 1984.
Spravochnik khimika (Chemist’s Handbook), Nikol’-skii, B.P., Ed., Moscow: Khimiya, 1964, vol. 3.
Moelwyn-Hughes, E.A., Physical Chemistry, New Nork: Pergamon, 1957. Translated under the title Fizicheskaya khimiya, Moscow: Inostrannaya Literatura, 1962, vol. 2, p. 771.
Libman, N.M., Zlobina, V.I., and Kuznetsov, S.G., Zh. Org. Khim., 1976, vol. 12, no. 2, p. 373.
Higachi, S., Tsuyama, H., Tanaka, S., and Kamada, H., Spectrochim. Acta, part A, 1974, vol. 30, p. 463.
Korshak, V.V., Vasnev, V.A., Vinogradova, S.V., Danashvili, M.M., and Sadimenko, A.P., Dokl. Akad. Nauk SSSR, 1980, vol. 253, no. 5, p. 1140.
Vereshchagin, A.I., Polyarizuemost’ molekul (Polarizability of Molecules), Moscow: Nauka, 1980.
Ioffe, B.V., Refraktometricheskie metody v khimii (Refractometric Methods in Chemistry), Leningrad: Khimiya, 1974.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.B. Bulgarevich, T.V. Burdastykh, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 1, pp. 118–129.
For communication LII, see [1].
Rights and permissions
About this article
Cite this article
Bulgarevich, S.B., Burdastykh, T.V. Molecular polarizability of organic compounds and their complexes: LIII. Molar volumes in solutions and steric structure of molecules of polyaryl compounds with bridging groups containing sp 2-and sp 3-hybridized carbon. Russ J Gen Chem 78, 112–122 (2008). https://doi.org/10.1134/S1070363208010192
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363208010192