Abstract
Gold particles are formed by photochemical reduction of HAuCl4 in the bulk of poly(butyl acrylate) elastomer films under the action of monochromatic light with the wavelengths of 254 and 365 nm with direct participation of the ester chromophore group of the polymer having intrinsic photosensitivity in the near-UV range (254 nm). On irradiation at the wavelength of 365 nm, the reduction of HAuCl4 is ineffective and stops at the stage of Au(I) formation. The physicomechanical properties of elastomer films modified with gold particles (tensile strength and relative elongation) were studied.
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Templeton, A.C., Pierton, J.J., Murray, R.W., and Mulvaney, P., J. Phys. Chem. B, 2000, vol. 104, no. 3, p. 564.
Li, K., Stockman, M.I., and Bergman, D., Phys. Rev. Lett., 2003, vol. 91, no. 22, p. 227402/1.
Schueler, P.A., Ives, J.T., DeLaCroix, F., Lacy, W.B., Becker, P.A., Li, J., Caldwell, K.D., Drake, B., and Harris, J.M., Anal. Chem., 1999, vol. 65, no. 22, p. 3177.
Solodovnik, V.D., Mikrokapsulirovanie (Microencapsulation), Moscow: Khimiya, 1980.
Hussain, I., Brust, M., Papworth, A.J., and Cooper, A.I., Langmuir, 2003, vol. 19, no. 11, p. 4831.
Yurkov, G.Yu., Kozinkin, A.V., Nedoseikina, T.I., Shuvaev, A.T., Vlasenko, V.G., Gubin, S.P., and Kosobudskii, I.D., Neorg. Mater., 2001, vol. 37, no. 10, p. 1180.
Boyes, S.G., Akgun, B., Brittain, W.J., and Foster, M.D., Macromolecules, 2003, vol. 36, no. 25, p. 9539.
Li, Z. and Liu, G., Langmuir, 2003, vol. 19, no. 25, p. 10480.
Boitsova, T.B., Gorbunova, V.V., and Loginov, A.V., Zh. Obshch. Khim., 1999, vol. 69, no. 12, p. 1937.
Isaeva, E.I., Gorbunova, V.V., Sirotinkin, N.V., Shchukarev, A.V., and Boitsova, T.B., Zh. Obshch. Khim., 2006, vol. 76, no. 5, p. 723.
Fox, R.B., Isaacs, L.G., Stokes, S., and Kagarise, R.E., J. Polym. Sci., Part A, 1964, vol. 2, no. 5, p. 2085.
Grassie, N., Torrance, B.J.D., and Colford, J.B., J. Polym. Sci., Part A, 1969, vol. 7, no. 6, p. 1425.
Guillet, J., An introduction to the Study of Photoprocesses in Macromolecules, New York: Wiley, 1985.
Monahan, A.R., J. Polym. Sci., Part A, 1966, vol. 3, no. 10, p. 2381.
Monahan, A.R., J. Polym. Sci., Part A, 1967, vol. 5, no. 9, p. 2333.
Bohren, C.F. and Huffman, D.R., Absorption and Scattering of Light by Small Particles, New York: Wiley, 1983.
Grassie, N., Chemistry of High Polymer Degradation Processes, London: Butterworth Scientific, 1956.
Wagner, C.D., Riggs, W.M., Davis, L.E., Moulder, J.F., and Muilenberg, G.E., Handbook of X-ray Photoelectron Spectroscopy, Eden Prairie, Minnesota: Perkin-Elmer, 1979.
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Original Russian Text © E.I. Isaeva, O.B. Svistunova, V.V. Gorbunova, T.B. Boitsova, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 12, pp. 1968–1971.
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Isaeva, E.I., Svistunova, O.B., Gorbunova, V.V. et al. Photochemical synthesis of gold nanoparticles in elastomer films of poly(butyl acrylate) latex. Russ J Gen Chem 77, 2113–2116 (2007). https://doi.org/10.1134/S1070363207120067
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DOI: https://doi.org/10.1134/S1070363207120067