Abstract
Zinc complexes of meso-trioctyltetrabenzomonoazaporphine and trans- and cis-meso-dioctyltetrabenzodiazaporphine were prepared by the reaction of 1,3-diiminoisoindoline with excess capric acid in the presence of zinc oxide. The corresponding metal-free porphines were prepared by treatment of the metal complexes with sulfuric acid. The spectra of the azaporphyrins prepared were examined.
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Galanin, N.E., Kudrik, E.V., and Shaposhnikov, G.P., Zh. Obshch. Khim., 2004, vol. 74, no. 2, p. 315.
Kopranenkov, V.N., Dashkevich, S.N., Shevtsov, V.K., and Luk”yanets, E.A., Khim. Geterotsikl. Soedin., 1984, no. 1, p. 61.
Galanin, N.E., Kudrik, E.V., and Shaposhnikov, G.P., Zh. Org. Khim., 2002, vol. 38, no. 8, p. 1251.
Donazello, M., Ercolani, C., Gaberkorn, A., Kudrik, E., Menegetti, M., Marcolongo, G., Rizolli, C., and Stuzhin, P., Chem. Eur. J., 2003, vol. 9, no. 17, p. 4009.
Kudrik, E.V., Islyaikin, M.K., and Frantseva, S.V., Zh. Obshch. Khim., 1997, vol. 67, no. 7, p. 1202.
Galanin, N.E., Kudrik, E.V., and Shaposhnikov, G.P., Zh. Obshch. Khim., 2000, vol. 70, no. 8, p. 1379.
Baumann, F., Binert, B., and Rosh, G.U.A., Angew. Chem., 1956, vol. 68, no. 1, p. 133.
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Original Russian Text © N.E. Galanin, G.P. Shaposhnikov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 11, pp. 1900–1904.
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Galanin, N.E., Shaposhnikov, G.P. meso-octyl-substituted tetrabenzoazaporphines and their zinc complexes: Synthesis and spectra. Russ J Gen Chem 77, 1951–1954 (2007). https://doi.org/10.1134/S1070363207110187
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DOI: https://doi.org/10.1134/S1070363207110187