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meso-octyl-substituted tetrabenzoazaporphines and their zinc complexes: Synthesis and spectra

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Abstract

Zinc complexes of meso-trioctyltetrabenzomonoazaporphine and trans- and cis-meso-dioctyltetrabenzodiazaporphine were prepared by the reaction of 1,3-diiminoisoindoline with excess capric acid in the presence of zinc oxide. The corresponding metal-free porphines were prepared by treatment of the metal complexes with sulfuric acid. The spectra of the azaporphyrins prepared were examined.

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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, G.P. Shaposhnikov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 11, pp. 1900–1904.

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Galanin, N.E., Shaposhnikov, G.P. meso-octyl-substituted tetrabenzoazaporphines and their zinc complexes: Synthesis and spectra. Russ J Gen Chem 77, 1951–1954 (2007). https://doi.org/10.1134/S1070363207110187

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  • DOI: https://doi.org/10.1134/S1070363207110187

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