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Synthesis and structure of the complex [Mo33-S)(μ2-S2)3(Et2NCS2)3]I

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Abstract

The structure of tri-μ2-disulfido-μ3-thiotris(diethyldithiocarbamato)-S,S′-triangle-trimolybdenum iodide [Mo33-S)(μ2-S2)3(Et2NCS2)3]I was determined. The compound was characterized by differential thermal analysis and IR, Raman, and X-ray electronic spectroscopy.

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References

  1. Mayor-Lopez, M.J., Weber, J., Hegetschweiler, K., Meienberger, M.D., Joho, F., Leoni, S., Nesper, R., Reiss, G.J., Frank, W., Kolesov, B.A., Fedin, V.P., and Fedorov, V.E., Inorg. Chem., 1998, vol. 37, no. 11, p. 2633.

    Article  Google Scholar 

  2. Fedin, V.P., Muller, A., Bege, Kh., Armatazh, A., Sokolov, M.H., Yarovoi, S.S., and Fedorov, V.E., Zh. Neorg. Khim., 1993, vol. 38, no. 10, p. 1677.

    CAS  Google Scholar 

  3. Zimmermann, H., Hegetschweiler, K., Keller, T., Gramlich, V., Schmalle, H.W., Petter, W., and Schneider, W., Inorg. Chem., 1991 vol. 30, no. 23, p. 4336.

    Article  CAS  Google Scholar 

  4. Il’inchik, E.A., Polyanskaya, T.M., Myakishev, K.G., Basova, T.V., and Kolesov, B.A., Zh. Obshch. Khim., 2002, vol. 72, no. 12, p. 1968.

    Google Scholar 

  5. Wang, M.-F., Quo, G.-C., Huang, J.-S., Zhuang, H.-H., Zhang, Q.-E., and Lu, J.-X., Chin. J. Struct. Chem. (Jiegou Huaxue), 1994, vol. 13, no. 3, p. 221.

    CAS  Google Scholar 

  6. Lu, C.-Z., Tong, W., Zhuang, H.-H., and Wu, D.-M., Chin. J. Struct. Chem. (Jiegou Huaxue), 1993, vol. 12, no. 2, p. 124.

    CAS  Google Scholar 

  7. Virovets, A.V. and Volkov, O.V., Zh. Strukt. Khim., 2000, vol. 40, no. 4, p. 866.

    Google Scholar 

  8. Allen, F.H. and Kennard, O., Chem. Design Automat. News, 1993, vol. 8, no. 1, p. 31.

    Google Scholar 

  9. Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

  10. Fedin, V.P., Sokolov, M.N., Geras’ko, O.A., Virovets, A.V., Podberezskaya, N.V., Fedorov, V.Ye., Inorg. Chim. Acta, 1992, vol. 192, no. 2, p. 153.

    Article  CAS  Google Scholar 

  11. Myakishev, K.G., Polyanskaya, T.M., and Il’inchik, E.A., Zh. Obshch. Khim., 2000, vol. 70, no. 10, p. 1585.

    Google Scholar 

  12. Folkesson, B. and Larsson, R., Chem. Scripta, 1976, vol. 10, no. 3, p. 105.

    CAS  Google Scholar 

  13. Wagner, C.D., J. Vac. Sci. Technol., 1978, vol. 15, no. 2, p. 518.

    Article  CAS  Google Scholar 

  14. Salyn’, Ya.V., Nefedov, V.I., Maiorova, A.G., and Kuznetsova, G.N., Zh. Neorg. Khim., 1978, vol. 23, no. 3, p. 829.

    Google Scholar 

  15. Grim, S.O. and Matienzo, L.J., Inorg. Chem., 1975, vol. 14, no. 5, p. 1014.

    Article  CAS  Google Scholar 

  16. Lindberg, B.J., Hamrin, K., Johansson, G., Fahlman, A., Nordling, C., and Siegbahn, K., Phys. Scripta, 1970, vol. 1, no. 3, p. 286.

    Article  CAS  Google Scholar 

  17. Il’inchik, E.A., Volkov, V.V., Volkov, O.V., Asanov, I.P., and Kolesov, B.A., Koord. Khim., 2000, vol. 26, no. 3, p. 192.

    Google Scholar 

  18. Sundberg, P., Larsson, R., and Folkesson, B., J. Electron Spectrosc., 1988, vol. 46, no. 1, p. 19.

    Article  CAS  Google Scholar 

  19. Patterson, T.A., Carver, J.C., Leyden, D.E., and Hercules, D.M., J. Phys. Chem., 1976, vol. 80, no. 15, p. 1700.

    Article  CAS  Google Scholar 

  20. Best, S.A., Brant, P., Feltham, R.D., Rauchfuss, Th.B., Roundhill, D.M., and Walton, R.A., Inorg. Chem., 1977, vol. 16, no. 8, p. 1976.

    Article  CAS  Google Scholar 

  21. Altomare, A., Cascarano, G., Giacovazzo, C., Guagliardi, A., Moliteruc, A.G.G., Burla, M.C., Polidori, G., Camalli, M., and Spagna, R., Abstracts of Papers, 17th Eur. Crystallogr. Meeting, Lissboa, 1997, p. 65.

  22. Sheldrick, G.M., SHELX-97, Release 97-2, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  23. Volkov, V.V. and Myakishev, K.G., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim., 1977, vol. 5, no. 12, p. 111.

    Google Scholar 

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Original Russian Text © E.A. Il’inchik, T.M. Polyanskaya, K.G. Myakishev, 2007, published in Zhurnal Obshchei Khimii, 2007, vol. 77, No. 7, pp. 1064–1071.

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Il’inchik, E.A., Polyanskaya, T.M. & Myakishev, K.G. Synthesis and structure of the complex [Mo33-S)(μ2-S2)3(Et2NCS2)3]I. Russ J Gen Chem 77, 1148–1154 (2007). https://doi.org/10.1134/S107036320707002X

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  • DOI: https://doi.org/10.1134/S107036320707002X

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