Skip to main content
SpringerLink
Log in

Thermodynamic properties of silicate glasses and melts: III. System Rb2O-B2O3-SiO2

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The composition of vapor over the system Rb2O-B2O3-SiO2 and the activities of RbBO in melts of this system at 1000 K were determined. The sign of deviations of the RbBO2 and Rb2SiO3 activities from ideality changes in the melts under study.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tyumina, N.G., Lopatin, S.I., Shugurov, S.M., and Stolyarova, V.L., Zh. Obshch. Khim., 2006, vol. 76, no. 12, p. 1966.

    Google Scholar 

  2. Sobolev, I.A., Ozhovan, M.I., Shcherbatova, T.D., and Batyukhina, O.G., Stekla dlya radioaktivnykh otkhodov (Glasses for Radioactive Waste), Moscow: Energoatomizdat, 1999.

    Google Scholar 

  3. Kazenas, E.K. and Tsvetkov, Yu.V., Isparenie oksidov (Evaporation of Oxides), Moscow: Nauka, 1997.

    Google Scholar 

  4. Furukawa, T. and White, W.B., J. Mater. Sci., 1981, vol. 16, no. 11, p. 2689.

    Article  CAS  Google Scholar 

  5. Yun, Y.H. and Bray, P.T., J. Non-Cryst. Solids, 1978, vol. 27, no. 2, p. 363.

    Article  CAS  Google Scholar 

  6. Asano, M., Kou, T., and Yasue, Y., Non-Cryst. Solids, 1987, vol. 92, nos. 2–3, p. 245.

    Article  CAS  Google Scholar 

  7. Asano, M., Harada, T., and Mizutani, Y., Phys. Chem. Glass, 1991, vol. 32, no. 4, p. 174.

    CAS  Google Scholar 

  8. Asano, M., Harada, T., and Mizutani, Y., J. Mater. Sci., 1991, vol. 26, p. 399.

    Article  CAS  Google Scholar 

  9. Asano, M. and Yasue, Y., J. Nucl. Mater., 1986, vol. 138, no. 1, p. 65.

    Article  CAS  Google Scholar 

  10. Asano, M. and Kou, T., Phys. Chem. Glasses, 1982, vol. 30, no. 1, p. 39.

    Google Scholar 

  11. Asano, M., Harada, T., and Mizutani, Y., J. Mass Spectr. Soc. Jpn., 1996, vol. 44, no. 1, p. 21.

    CAS  Google Scholar 

  12. Stolyarova, V.L., Lopatin, S.I., Belousova, O.L., and Grishchenko, L.V., Fiz. Khim. Stekla, 2006, vol. 32, no. 1, p. 80.

    Google Scholar 

  13. Gorokhov, L.N., Gusarov, A.V., Makarov, A.V., and Nikitin, O.T., Teplofiz. Vys. Temp., 1971, vol. 9, no. 6, p. 1173.

    CAS  Google Scholar 

  14. Makarov, A.V. and Nikitin, O.T., Vestn. Mosk. Gos. Univ., 1974, no. 5, p. 533.

  15. Stolyarova, V.L. and Lopatin, S.I., Fiz. Khim. Stekla, 2004, vol. 30, no. 2, p. 204.

    Google Scholar 

  16. Makarov, A.V. and Nikitin, O.T., Teplofiz. Vys. Temp., 1971, vol. 9, no. 5, p. 1073.

    CAS  Google Scholar 

  17. Asano, M., Yasue, Y., and Kubo, K., J. Nucl. Sci. Technol., 1984, vol. 21, no. 8, p. 614.

    Article  CAS  Google Scholar 

  18. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu: Spravochnik (Dissociation Energies of Chemical Bonds: Ionization Potentials and Electron Affinities: Handbook), Kondrat’ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

  19. Stolyarova, V.L. and Semenov, G.A., Mass Spectrometric Study of the Vaporization of Oxide Systems, Chichester: Wiley, 1994.

    Google Scholar 

  20. Anfilogov, V.N., Bykov, V.N., and Osipov, A.A., Silikatnye rasplavy (Silicate Melts), Moscow: Nauka, 2005.

    Google Scholar 

  21. Paule, R.C. and Mandel, J., Pure Appl. Chem., 1972, vol. 31, no. 3, p. 397.

    Google Scholar 

  22. Stolyarova, V.L., Lopatin, S.I., and Plotnikov, E.N., Fiz. Khim. Stekla, 2006, vol. 32, no. 5, p. 742.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    S. I. Lopatin, S. M. Shugurov & V. L. Stolyarova

Authors
  1. S. I. Lopatin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. M. Shugurov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. L. Stolyarova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © S.I. Lopatin, S.M. Shugurov, V.L. Stolyarova, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 6, pp. 905–909.

For communication II, see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lopatin, S.I., Shugurov, S.M. & Stolyarova, V.L. Thermodynamic properties of silicate glasses and melts: III. System Rb2O-B2O3-SiO2 . Russ J Gen Chem 77, 997–1001 (2007). https://doi.org/10.1134/S1070363207060060

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363207060060

Keywords

Search

Navigation