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Molecular structure of complexes with bifurcated hydrogen bond: IV. Solvate H-complexes of N-methyltrifluoromethanesulfonamide in aprotic protophilic media

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Abstract

Analysis of the IR spectra of N-methyltrifluoromethanesulfonamide, as well as quantum-chemical calculations of solvate complexes of its monomer and open-chain dimer have demonstrated inadequacy of the model assuming the presence in protophilic solvents of a 1:1 monomer H-complex only. A model is suggested, which is based on an equilibrium between the 1:1 monomer H-complexes and open-chain dimer complexes of variable composition. The proposed model is much better consistent with experimental data.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    I. V. Sterkhova, N. N. Chipanina, B. A. Shainyan & V. K. Turchaninov

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  1. I. V. Sterkhova
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  2. N. N. Chipanina
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  3. B. A. Shainyan
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  4. V. K. Turchaninov
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Additional information

Original Russian Text © I.V. Sterkhova, N.N. Chipanina, B.A. Shainyan, V.K. Turchaninov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 1, pp. 79–89.

For communication III, see [1].

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Sterkhova, I.V., Chipanina, N.N., Shainyan, B.A. et al. Molecular structure of complexes with bifurcated hydrogen bond: IV. Solvate H-complexes of N-methyltrifluoromethanesulfonamide in aprotic protophilic media. Russ J Gen Chem 77, 73–83 (2007). https://doi.org/10.1134/S1070363207010100

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  • DOI: https://doi.org/10.1134/S1070363207010100

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