Abstract
Hydrosilylation of allyl glycidyl ether with triethoxysilane in presence of Speier’s catalyst leads to triethoxy(3-glycidoxypropyl)silane and triethoxy(2-glycidoxy-1-methylethyl)silane and is accompanied by isomerization of allyl glycidyl ether and cleavage of the oxirane ring and the ether bond. An effect of admixtures in allyl glycidyl ether on the process is revealed. Some other hydrosilylation catalysts and additives to Speier’s catalyst are studied
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Original Russian Text © E.A. Chernyshev, Z.V. Belyakova, L.K. Knyazeva, N.N. Khromykh, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 1, pp. 61–67.
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Chernyshev, E.A., Belyakova, Z.V., Knyazeva, L.K. et al. Hydrosilylation of allyl glycidyl ether with triethoxysilane. Russ J Gen Chem 77, 55–61 (2007). https://doi.org/10.1134/S1070363207010082
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DOI: https://doi.org/10.1134/S1070363207010082