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Kinetics of oxidation of lower olefins with Fe(III) aqua ions in the presence of the Pd/ZrO2/SO4 precatalyst in a chloride-free system

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Abstract

The kinetics of oxidation of ethene, propene, and 1-butene with Fe(III) aqua ions to the corresponding carbonyl compounds in the presence of the 1% Pd/ZrO2/SO4 precatalyst in aqueous perchloric acid at 40–80°C was studied. The oxidation rate increases in the order C2H4 < C4H8 < C3H6 and with increasing catalyst weight and in the acid and Fe(III) concentrations; it is independent of the olefin pressure. The ethene oxidation rate is described by the Michaelis-Menten equation. In the case of 1-butene, the reaction is accompanied by migration of the double bond with the formation of 2-butene.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Technical University, Moskovskii pr. 26, St. Petersburg, 198013, Russia

    V. V. Potekhin & V. A. Matsura

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  1. V. V. Potekhin
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  2. V. A. Matsura
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Original Russian Text © V.V. Potekhin, V.A. Matsura, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 6, pp. 895–900.

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Potekhin, V.V., Matsura, V.A. Kinetics of oxidation of lower olefins with Fe(III) aqua ions in the presence of the Pd/ZrO2/SO4 precatalyst in a chloride-free system. Russ J Gen Chem 76, 857–861 (2006). https://doi.org/10.1134/S107036320606003X

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  • DOI: https://doi.org/10.1134/S107036320606003X

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