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Reaction of bis(phenylethynyl)itterbium with tetraphenylantimony halides

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Abstract

Phenylethynyl itterbium derivative (PhC≡C)2Yb(THF)2 reacts with tetraphenylantimony halides in tetrahydrofuran (THF) at room temperature to form triphenylantimony, phenylacetylene, benzene, and phenylethynylitterbium PhC≡CYbX(THF)4 and itterbium YbX2(THF)4 halides; X = Cl, Br, I. The reduction of the antimony derivative is accompanied with the generation of phenyl and phenylethynyl radicals

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Authors and Affiliations

  1. Nizhnii Novgorod State Pedagogical University, ul. Ul’yanova, Nizhnii Novgorod, 603950, Russia

    S. F. Zhiltsov & N. A. Pimenova

  2. Lobachevskii Nizhnii Novgorod State University, Nizhnii Novgorod, Russia

    V. A. Morgunova

Authors
  1. S. F. Zhiltsov
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  2. N. A. Pimenova
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  3. A. V. Gushchin
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  4. V. A. Morgunova
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Additional information

Original Russian Text © S.F. Zhiltsov, N.A. Pimenova, A.V. Gushchin, V.A. Morgunova, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 5, pp. 741–743.

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Zhiltsov, S.F., Pimenova, N.A., Gushchin, A.V. et al. Reaction of bis(phenylethynyl)itterbium with tetraphenylantimony halides. Russ J Gen Chem 76, 705–707 (2006). https://doi.org/10.1134/S1070363206050070

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  • DOI: https://doi.org/10.1134/S1070363206050070

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