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Catalytic oxidation of Fe(II) aqua ions with atmospheric oxygen in the presence of Pd(II) tetraaqua complex and an aromatic compound

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Abstract

The effect of a series of aromatic compounds (toluene, benzyl alcohol, benzonitrile, phenylacetonitrile, and o-cyanotoluene) in a concentration of 0.01 M on the oxidation of Fe(II) aqua ions with oxygen in the presence of Pd(II) tetraaqua complex at 25–70°C was revealed. In the presence of an aromatic compound, palladium black is not formed, which results in an increased yield of Fe(III) in the Pd-catalyzed oxidation of Fe(II) with oxygen in a perchloric acid medium. A scheme involving the formation of a complex of palladium species in an intermediate oxidation state with arene and molecular oxygen was suggested.

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References

  1. Potekhin, V.V., Matsura, V.A., Solov’eva, S.N., and Potekhin, V.M., Kinet. Katal., 2004, vol. 45, no. 3, p. 407.

    Google Scholar 

  2. Potekhin, V.V., Solov’eva, S.N., and Potekhin, V.M., Zh. Obshch. Khim., 2004, vol. 74, no. 5, p. 709.

    Google Scholar 

  3. Potekhin, V.V., Solov’eva, S.N., and Potekhin, V.M., Izv. Ross. Akad. Nauk, Ser. Khim., 2003, no. 12, p. 2420.

  4. Allegra, G., Immirzi, A., and Porri, L., J. Am. Chem. Soc., 1965, vol. 87, no. 6, p. 1394.

    Article  CAS  Google Scholar 

  5. Allegra, G., Tettamant, G., Immirzi, A., Porri, L., and Vitulli, G., J. Am. Chem. Soc., 1970, vol. 92, no. 2, p. 289.

    Article  CAS  Google Scholar 

  6. Potekhin, V.V., Solov’eva, S.N., and Potekhin, V.M., Zh. Obshch. Khim., 2004, vol. 74, no. 5, p. 866.

    Google Scholar 

  7. Valentine, J.S., Chem. Rev., 1973, vol. 73, no. 3, p. 235.

    Article  CAS  Google Scholar 

  8. Kukushkin, Yu.N., Reaktsionnaya sposobnost’ koordinatsionnykh soedinenii (Reactivity of Coordination Compounds), Leningrad: Khimiya, 1987.

    Google Scholar 

  9. Shilov, A.E. and Shul’pin, G.B., Aktivatsiya i kataliticheskie reaktsii uglevodorodov (Activation and Catalytic Reactions of Hydrocarbons), Moscow: Nauka, 1995.

    Google Scholar 

  10. Moiseev, I.I., J. Mol. Catal. (A), 1997, vol. 127, no. 1, p. 1.

    Article  CAS  Google Scholar 

  11. Elding, L., Helv. Chim. Acta, 1984, vol. 67, no. 6, p. 1453.

    Article  Google Scholar 

  12. Marczenko, Z., Kolorymetryczne oznaczanie pierwiastkow, Warsaw: Naukowa-Techniczne, 1968.

    Google Scholar 

  13. Ginzburg, S.I., Analiticheskaya khimiya platinovykh metallov (Analytical Chemistry of Platinum Metals), Moscow: Nauka, 1972.

    Google Scholar 

Download references

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Technical University, Moskovskii pr. 26, St. Petersburg, 198013, Russia

    V. V. Potekhin, S. N. Solov’eva & V. M. Potekhin

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  1. V. V. Potekhin
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  2. S. N. Solov’eva
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  3. V. M. Potekhin
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Original Russian Text © V.V. Potekhin, S.N. Solov’eva, V.M. Potekhin, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 5, pp. 730–736.

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Potekhin, V.V., Solov’eva, S.N. & Potekhin, V.M. Catalytic oxidation of Fe(II) aqua ions with atmospheric oxygen in the presence of Pd(II) tetraaqua complex and an aromatic compound. Russ J Gen Chem 76, 694–699 (2006). https://doi.org/10.1134/S1070363206050057

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  • DOI: https://doi.org/10.1134/S1070363206050057

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