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meso-trans-Diphenyldi(2-quinolyl)tetrabenzoporphine and its zinc complex: Synthesis and spectra

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Abstract

(3-Oxoisoindolenyl)(3-oxoisoindolinylidene)phenylmethane and (3-oxoisoindolenyl)(3-oxoisoindolinylidene)(2-quinolyl)methane were prepared by condensation of phthalimide with phenylacetic acid or 2-methylquinoline, respectively, in the presence of zinc oxide. From these products, the zinc complex of meso-trans-diphenyldi(2-quinolyl)tetrabenzoporphine was prepared by two alternative pathways. Demetallation of this complex yielded free meso-trans-diphenyldi(2-quinolyl)tetrabenzoporphine. The spectra of the compounds prepared were examined.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Engineering, pr. F. Engelsa 7, Ivanovo, 153460, Russia

    N. E. Galanin, E. V. Kudrik & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. E. V. Kudrik
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  3. G. P. Shaposhnikov
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Original Russian Text © N.E. Galanin, E.V. Kudrik, G.P. Shaposhnikov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 151–155.

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Galanin, N.E., Kudrik, E.V. & Shaposhnikov, G.P. meso-trans-Diphenyldi(2-quinolyl)tetrabenzoporphine and its zinc complex: Synthesis and spectra. Russ J Gen Chem 76, 148–152 (2006). https://doi.org/10.1134/S1070363206010282

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  • DOI: https://doi.org/10.1134/S1070363206010282

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