Abstract
Hydrosilylation of tetramethyldivinyldisiloxane with pentamethyl-and tetramethyldisiloxane in the presence of photoactivated alkene and sulfoxide platinum(II) complexes was studied. The most active photoactivated catalysts are bis-sulfoxide platinum complexes; an additional photosensitive center, the oxalate ligand, enhances the effect of photoirradiation.
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Original Russian Text © D.A. Vekki, N.K. Skvortsov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 119–124.
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de Vekki, D.A., Skvortsov, N.K. Hydrosilylation of low-molecular siloxanes in the presence of photactivated alkene and sulfoxide platinum(II) complexes. Russ J Gen Chem 76, 116–121 (2006). https://doi.org/10.1134/S107036320601021X
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DOI: https://doi.org/10.1134/S107036320601021X