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Preparation of complexes of 1-amino-6,7-O-cyclohexylidene-4-azaheptane with transition metal acetates

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Abstract

1-Amino-6,7-O-cyclohexylidene-4-azaheptane (L) has been synthesized starting from 1-chloro-2,3-O-cyclohexylidenepropane prepared by the reaction of epichlorohydrin with cyclohexanone, catalyzed by BF3OEt2. Complexes of this ligand with Co(II), Ni(II) and Cu(II) acetates were prepared. The structures of the ligand and its complexes are proposed based on the elemental analyses, IR, UV-VIS, and 1H and 13C NMR spectra, magnetic susceptibilities, and conductomety data.

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Authors and Affiliations

  1. Çanakkale 18 Mart University of Arts and Sciences, Çanakkale, 17100, Turkey

    Ö. F. Öztirk & E. Özdemir

  2. Firat University, Elaziǧ, 23119, Turkey

    M. Şekerci

Authors
  1. Ö. F. Öztirk
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  2. M. Şekerci
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  3. E. Özdemir
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Original Russian Text © O.F. Öztirk, M. Şekerci, E. Özdemir, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 36–40.

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Öztirk, Ö.F., Şekerci, M. & Özdemir, E. Preparation of complexes of 1-amino-6,7-O-cyclohexylidene-4-azaheptane with transition metal acetates. Russ J Gen Chem 76, 33–36 (2006). https://doi.org/10.1134/S1070363206010075

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  • DOI: https://doi.org/10.1134/S1070363206010075

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