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Redox-Active Tin(IV) Complexes Based on Sterically Hindered Catecholate Ligands

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Abstract

The oxidative addition of sterically hindered 3,6-dicyclohexyl-o-benzoquinone (L1), 3,5-di-tert-octyl-o-benzoquinone (L2), 4-tert-octyl-o-benzoquinone (L3), and 3,5-bis(2-phenylpropyl)-o-benzoquinone (L4) to tin(II) chloride in THF affords the corresponding tin(IV) catecholate complexes with the general formula RCatSnCl2·2THF, where Cat is the catecholate fragment; and R is 3,6-с-Hex (I), 3,5-tert-Oct (II), 4-tert-Oct (III), and 3,5-C(Me)2Ph (IV), regardless of the molar ratio of the starting reactants. The molecular structures of substituted o-benzoquinone L4 and complexes I and III in the crystalline form are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2259370 (L4), 2259371 (I), and 2259372 (III)). The oxidation–reduction properties of synthesized compounds I–IV are studied by cyclic voltammetry.

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ACKNOWLEDGMENTS

The work was carried out using the equipment of the Center for Collective Use “Analytical Center of Institute of Organometallic Chemistry of Russian Academy of Sciences” and supported by the project “Provision of Development of Material Technical Infrastructure of Centers for Collective Use of Scientific Equipment” (unique identifier RF–2296.61321X0017, agreement no. 075-15-2021-670).

Funding

This work was supported by the Council on Grants of the President of the Russian Federation for state support of young Russian scientists and leading scientific schools of the Russian Federation (project no. NSh-403.2022.1.3). The study of the experimental–theoretical electron density was supported by the Russian Science Foundation, project no. 21-13-00336.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    S. V. Baryshnikova, M. V. Arsen’ev, N. O. Druzhkov, G. K. Fukin, E. V. Baranov & A. V. Piskunov

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  1. S. V. Baryshnikova
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  2. M. V. Arsen’ev
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  3. N. O. Druzhkov
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Correspondence to S. V. Baryshnikova.

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Translated by E. Yablonskaya

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Baryshnikova, S.V., Arsen’ev, M.V., Druzhkov, N.O. et al. Redox-Active Tin(IV) Complexes Based on Sterically Hindered Catecholate Ligands. Russ J Coord Chem 50, 49–60 (2024). https://doi.org/10.1134/S1070328423600778

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