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Synthesis, Structure, and Photoluminescence of Zinc(II) and Silver(I) Complexes with 2-(3,5-Dimethyl-1H-pyrazol-1-yl)-4,6-Diphenylpyrimidine

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Abstract

The complexes [AgL2]PF6 (I) and [ZnLCl2] (II) (L = 2-(3,5-dimethyl-1H-pyrazol-1-yl)-4,6-diphenylpyrimidine) were prepared by the reaction of zinc(II) chloride or silver(I) hexafluorophosphate with L (M : L molar ratio of 1 : 1 or 1 : 2) in organic solvents. The structure of the complexes was determined by X-ray diffraction (CIF file CCDC no. 2118498). In both complexes, L is coordinated in the bidentate chelating manner; the coordination unit is a distorted tetrahedron. The coordination unit of II is formed by one coordinated molecule L and two chloride ions (ZnN2Cl2); in the case of silver(I), there are two molecules L (AgN4). The photoluminescent properties of compounds I and II in the solid state were studied. The compound II shows fluorescence (1.3, 11 ns) in the blue spectral range (λmax = 378 nm; quantum yield of 7.8%). The maximum at 530 nm in the photoluminescence spectrum of I is red-shifted by ~140–160 nm relative to the emission maxima of L and II. The complex I shows white light emission (1.6, 11 ns, quantum yield of 5.5%), which is due to intraligand transitions perturbed by the coordination of L to the silver atom. The photostability of I was studied at 300 and 80 K.

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ACKNOWLEDGMENTS

The authors are grateful to T.S. Sukhikh for providing the data measured at the X-ray diffraction Center for Collective Use of the Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, to I.V. Yushina for recording the diffuse reflectance spectra, to A.A. Sha-povalova for measuring the IR spectra, to A.P. Zubareva for CHN analysis, to P.E. Plyusnin for thermogravimetric analysis, and to A.O. Matveeva for measuring the X-ray diffraction patterns.

Funding

This study was supported by a grant of President of the Russian Federation for young scientists (project no. MK-1219.2020.3) and by the Ministry of Science and Higher Education of the Russian Federation (project nos. 121031700315-2, 121031700321-3, 121031700314-5, and 121031700313-8).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    K. A. Vinogradova, M. I. Rakhmanova, M. B. Bushuev, N. V. Pervukhina, D. Yu. Naumov & S. A. Martynova

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. B. Nikolaenkova & V. P. Krivopalov

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  1. K. A. Vinogradova
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  2. M. I. Rakhmanova
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  3. E. B. Nikolaenkova
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  5. M. B. Bushuev
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Correspondence to K. A. Vinogradova.

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Translated by Z. Svitanko

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Vinogradova, K.A., Rakhmanova, M.I., Nikolaenkova, E.B. et al. Synthesis, Structure, and Photoluminescence of Zinc(II) and Silver(I) Complexes with 2-(3,5-Dimethyl-1H-pyrazol-1-yl)-4,6-Diphenylpyrimidine. Russ J Coord Chem 48, 301–310 (2022). https://doi.org/10.1134/S1070328422050098

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