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Synthesis and Crystal Structure of {\({\text{Eu}}_{2}^{\text{III}}\)Cd2}, {\({\text{Tb}}_{2}^{{{\text{III}}}}\)Cd2} and {\(\text{Eu}_{2}^{\text{III}}\)Zn2} Complexes with Pentafluorobenzoic Acid Anions and Acetonitrile

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Abstract

Methods for the synthesis were developed and new homo- and heterometallic cadmium ([Eu2Cd2(MeCN)4(C6F5COO)10] (I), [Tb2Cd2(MeCN)6(C6F5COO)10]·4MeCN (II)) and zinc ([Zn(H2O)(C6F5COO)2] (III), [Eu2Zn2(MeCN)4(C6F5COO)10] (IV)) complexes were characterized. These complexes can be used as precursors for the synthesis of compounds with N-donor ligands. Complexes I and II differ in the coordination of the MeCN molecule, which is coordinated in II by each Tb3+ ion. Also, additional coordination of MeCN induces a greater distortion of the {Tb2Cd2} metal core of II. The crystal packing in I–IV is stabilized by numerous intermolecular O…H, F…F, C–H…F, and C–H…O contacts. The new compounds were characterized by single crystal X-ray diffraction (CCDC no. 2076524 (I), 2082731 (II), 2082803 (III), 2076525 (IV)), IR spectroscopy, C,H,N elemental analysis, and powder X-ray diffraction.

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REFERENCES

  1. Mironova, O.A., Ryadun, A.A., Sukhikh, T.S., et al., New J. Chem., 2020, vol. 44, p. 19769.

    Article  CAS  Google Scholar 

  2. Zhao, S.-N., Wang, G., Poelman, D., et al., Materials, 2018, vol. 11, no. 4, p. 572.

    Article  Google Scholar 

  3. Runowski, M., Woz’ny, P., Lis, S., et al., Adv. Mater. Technol., 2020, vol. 5, p. 1901091.

    Article  CAS  Google Scholar 

  4. Wu, S., Lin, Y., Liu, J., et al., Adv. Funct. Mater., 2018, vol. 28, no. 17, p. 1707169.

  5. Sidorov, A.A., Gogoleva, N.V., Bazhina, E., et al., Pure Appl. Chem., 2020, vol. 92, no. 7, p. 1093.

  6. Rubtsova, I.K., Melnikov, S.N., Shmelev, M.A., et al., Mendeleev Commun., 2020, vol. 30, no. 6, p. 722.

  7. Sapianik, A.A. and Fedin, V.P., Russ. J. Coord. Chem., 2020, vol. 46, no. 7, p. 443. https://doi.org/10.1134/S1070328420060093

  8. Shmelev, M.A., Gogoleva, N.V., Sidorov, A.A., et al., Russ. J. Coord. Chem., 2020, vol. 46, no. 1, p. 1. https://doi.org/10.1134/S1070328420010078

    Article  CAS  Google Scholar 

  9. Kalyakina, A.S., Utochnikova, V.V., Bushmarinov, I.S., et al., Chem.-Eur. J., 2015, vol. 21, no. 49, p. 17921.

    Article  CAS  Google Scholar 

  10. Utochnikova, V.V. and Kuzmina, N.P., Russ. J. Coord. Chem., 2016, vol. 42, no. 10, p. 679. https://doi.org/10.1134/S1070328416090074

    Article  CAS  Google Scholar 

  11. Shmelev, M.A., Gogoleva, N.V., Kuznetsova, G.N., et al., Russ. J. Coord. Chem., 2020, vol. 46, no. 8, p. 557. https://doi.org/10.1134/S1070328420080060

    Article  CAS  Google Scholar 

  12. Bondarenko, M.A., Novikov, A.S., Korolkov, I.V., et al., Inorg. Chim. Acta, 2021, vol. 524, p. 120436.

    Article  CAS  Google Scholar 

  13. Bondarenko, M.A., Novikov, A.S., Sakhapov, I.F., et al., J. Mol. Struct., 2021, vol. 1234, p. 130199.

    Article  CAS  Google Scholar 

  14. Rozhkov, A.V., Krykova, M.A., Ivanov, D.M., et al., Angew. Chem. Int. Ed., 2019, vol. 58, no. 13, p. 4164.

    Article  CAS  Google Scholar 

  15. Bear, J.C., Cockcroft, J.K., and Williams, J.H., J. Am. Chem. Soc., 2020, vol. 142, no. 4, p. 1731.

    Article  CAS  Google Scholar 

  16. Bazhina, E.S., Nikiforova, M.E., Aleksandrov, G.G., et al., Russ. Chem. Bull., 2012, vol. 61, p. 1084.

    Article  CAS  Google Scholar 

  17. Shmelev, M.A., Kiskin, M.A., and Voronina, J.K., et al., Materials, 2020, vol. 13, p. 5689.

    Article  CAS  Google Scholar 

  18. Shmelev, M.A., Gogoleva, N.V., Sidorov, A.A., et al., Russ. J. Coord. Chem., 2020, vol. 46, no. 7, p. 493. https://doi.org/10.1134/S1070328420070076

    Article  Google Scholar 

  19. Shmelev, M.A., Kuznetsova, G.N., Gogoleva, N.V., et al., Izv. Akad. Nauk. Ser. Khim., 2021, no. 5, p. 830.

  20. Shmelev, M.A., Gogoleva, N.V., Sidorov, A.A., et al., Chem. Select., 2020, vol. 5, p. 8475.

    CAS  Google Scholar 

  21. Shmelev, M.A., Gogoleva, N.V., Sidorov, A.A., et al., Inorg. Chim. Acta, 2021, vol. 515, p. 120050.

    Article  CAS  Google Scholar 

  22. Cui, Y., Chen, G., Ren, J., Qian, Y., and Huang, J., Inorg. Chem., 2000, vol. 39, no. 18, p. 4165.

  23. Kiraev, S., Nikolaevskii, S.A., Kiskin, M.A., et al., Inorg. Chim. Acta, 2018, vol. 477, p. 15.

    Article  CAS  Google Scholar 

  24. Wu, B. and Hou, T., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2010, vol. 66, p. m457.

    Article  CAS  Google Scholar 

  25. Cui, Y., Zheng, F., Qian, Y., et al., Inorg. Chim. Acta, 2001, vol. 315, no. 2, p. 220.

    Article  CAS  Google Scholar 

  26. Cui, Y., Chen, J.-T., Long, D.-L., et al., Dalton Trans., 1998, p. 2955.

  27. Wu, B. and Zhao, C.-X., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2010, vol. 66, p. m1075.

    Article  CAS  Google Scholar 

  28. Boyle, T.J., Raymond, R., Boye, D.M., et al., Dalton Trans., 2010, vol. 39, p. 8050.

    Article  CAS  Google Scholar 

  29. Kiskin, M.A., Varaksina, E.A., Taydakov, I.V., and Eremenko, I.L., Inorg. Chim. Acta, 2018, vol. 482, p. 85.

    Article  CAS  Google Scholar 

  30. Goldberg, A., Kiskin, M., Shalygina, O., et al., Chem. Asian J., 2016, vol. 11, no. 4, p. 604.

    Article  CAS  Google Scholar 

  31. Larionov, S.V., Glinskaya, L.A., Leonova, T.G., et al., Russ. J. Coord. Chem., 2009, vol. 35, p. 808. https://doi.org/10.1134/S1070328409110025

    Article  CAS  Google Scholar 

  32. SMART (control) and SAINT (integration). Software. Version 5.0, Madison: Bruker AXS Inc., 1997.

  33. Sheldrick, G.M., SADABS, Madison: Bruker AXS Inc., 1997.

    Google Scholar 

  34. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  35. Dolomanov, O.V., Bourhis, L.J., and Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  36. Alvarez, S. and Llunell, M., Dalton Trans., 2000, no. 19, p. 3288.

  37. Casanova, D., Llunell, M., Alemany, P., and Alvarez, S., Chem.-Eur. J., 2005, vol. 11, p. 1479.

    Article  CAS  Google Scholar 

  38. Yakushev, I.A., Stolarov, I.P., Cherkashina, N.V., et al., Inorg. Chim. Acta, 2020, vol. 508, p. 119631.

    Article  CAS  Google Scholar 

  39. Wu, B., Lu, W., and Zheng, X., J. Coord. Chem., 2002, vol. 55, no. 5, p. 497.

    Article  CAS  Google Scholar 

  40. Chen, F., Lu, W., Zhu, Y., et al., J. Coord. Chem., 2009, vol. 62, no. 5, p. 808.

    Article  CAS  Google Scholar 

  41. Wang, Y.M., Rui, Y.W., Wang, X., et al., J. Phys. Chem. Solids, 2017, vol. 104, p. 221.

    Article  CAS  Google Scholar 

  42. Zorina-Tikhonova, E.N., Gogoleva, N.V., Sidorov, A.A., et al., Eur. J. Inorg. Chem., 2017, no. 10, p. 1396.

  43. Zorina-Tikhonova, E.N., Chistyakov, A.S., Kiskin, M.A., et al., IUCrJ, 2018, vol. 5, p. 293.

    Article  CAS  Google Scholar 

  44. Kiskin, M., Zorina-Tikhonova, E., Kolotilov, S., et al., Eur. J. Inorg. Chem., 2018, no. 12, p. 1356.

  45. Zheng, Y.-Z., Evangelisti, M., Tuna, F., and Winpenny, R.E.P., J. Am. Chem. Soc., 2012, vol. 134, no. 2, p. 1057.

    Article  CAS  Google Scholar 

  46. Burkovskaya, N.P., Orlova, E.V., Kiskin, M.A., et al., Russ. Chem. Bull., 2011, p. 2442.

  47. Egorov, E.N., Mikhalev, E.A., Kiskin, M.A., et al., Russ. Chem. Bull., 2013, p. 2141.

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Funding

This study was supported by the Ministry of Education and Science of Russia within the framework of the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences. Single crystal and powder X-ray diffraction, IR spectroscopy, and C,H,N,S analysis were carried out using the equipment of the Center for Collective Use of the Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, supported by the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. A. Shmelev, Yu. K. Voronina, N. V. Gogoleva, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    I. L. Eremenko

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  1. M. A. Shmelev
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  2. Yu. K. Voronina
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  3. N. V. Gogoleva
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  4. M. A. Kiskin
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  5. A. A. Sidorov
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  6. I. L. Eremenko
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Correspondence to M. A. Shmelev.

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Translated by Z. Svitanko

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Shmelev, M.A., Voronina, Y.K., Gogoleva, N.V. et al. Synthesis and Crystal Structure of {\({\text{Eu}}_{2}^{\text{III}}\)Cd2}, {\({\text{Tb}}_{2}^{{{\text{III}}}}\)Cd2} and {\(\text{Eu}_{2}^{\text{III}}\)Zn2} Complexes with Pentafluorobenzoic Acid Anions and Acetonitrile. Russ J Coord Chem 48, 224–232 (2022). https://doi.org/10.1134/S1070328422040042

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