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Novel oxovanadium(iv) heterochelate complexes: synthesis, structure, ESR spectra, and photoluminescence properties

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Abstract

The reactions of oxovanadium(iv) salts with dimethylmalonate anions (H2Dmm — C3H6(COOH)2) and chelating N-donor ligands (2,2′:6′,2″-terpyridine (terpy), 2,2′-bipyridine (bpy)) led to the formation of new mononuclear heterochelate complexes [VO(Dmm)(terpy)]·4H2O (1) and [VO(Dmm)(bpy)(H2O)] (2). The structures of the synthesized compounds were determined by X-ray diffraction. The ESR spectra of the compounds at 293 and 100 K were analyzed and simulated. The photoluminescence properties were investigated.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov, N. N. Efimov, E. A. Ugolkova, V. V. Minin, S. A. Kozyukhin, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

Authors
  1. E. S. Bazhina
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  2. M. E. Nikiforova
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  3. G. G. Aleksandrov
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  4. N. N. Efimov
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  5. E. A. Ugolkova
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  6. V. V. Minin
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  7. S. A. Kozyukhin
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  8. A. A. Sidorov
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  9. V. M. Novotortsev
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  10. I. L. Eremenko
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Corresponding author

Correspondence to E. S. Bazhina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1078—1085, June, 2012.

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Bazhina, E.S., Nikiforova, M.E., Aleksandrov, G.G. et al. Novel oxovanadium(iv) heterochelate complexes: synthesis, structure, ESR spectra, and photoluminescence properties. Russ Chem Bull 61, 1084–1092 (2012). https://doi.org/10.1007/s11172-012-0147-x

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  • DOI: https://doi.org/10.1007/s11172-012-0147-x

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