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Synthesis, Structure, and Properties of Copper(II), Nickel(II), and Cobalt(II) Ketoiminate Chelates. Molecular and Crystal Structures of Bis[2-nitro-3-(8-quinolylimino)prop-1-enoxy]cobalt(II)

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Abstract

β-Aminovinyl ketone (2-nitro-3-(8-quinolylamino)prop-2-enal) was synthesized by condensation of nitromalondialdehyde with 8-aminoquinoline. The reactions of β-aminovinyl ketone with copper, nickel, and cobalt acetates in methanol gave metal complexes. The spectral and magnetic characteristics of preparatively isolated compounds were studied. The structure of cobalt(II) chelate was determined on the basis of X-ray diffraction study (CIF file CCDC no. 2109263).

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Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment of the Southern Federal University in the field of science, project 0852-2020-0031).

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia

    T. V. Kovaleva, A. I. Uraev, A. S. Burlov & G. S. Borodkin

  2. Moscow State University, 119991, Moscow, Russia

    K. A. Lyssenko

  3. Research Institute of Physics, Southern Federal University, 344090, Rostov-on-Don, Russia

    V. G. Vlasenko

  4. Southern Scientific Center, Russian Academy of Sciences, 344006, Rostov-on-Don, Russia

    D. A. Garnovskii

Authors
  1. T. V. Kovaleva
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  2. A. I. Uraev
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  3. K. A. Lyssenko
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  4. V. G. Vlasenko
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  5. A. S. Burlov
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  6. G. S. Borodkin
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  7. D. A. Garnovskii
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Correspondence to A. I. Uraev.

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Translated by Z. Svitanko

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Kovaleva, T.V., Uraev, A.I., Lyssenko, K.A. et al. Synthesis, Structure, and Properties of Copper(II), Nickel(II), and Cobalt(II) Ketoiminate Chelates. Molecular and Crystal Structures of Bis[2-nitro-3-(8-quinolylimino)prop-1-enoxy]cobalt(II). Russ J Coord Chem 48, 210–217 (2022). https://doi.org/10.1134/S1070328422040029

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