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Synthesis and Structure of Tetra(para-tolyl)antimony Dicyanodiiodoaurate [p-Tol4Sb][Au(CN)2I2] and Alkyltriphenylphosphonium Dicyanodiiodoaurates [Ph3PAlk][Au(CN)2I2], Alk = Me, CH2CN

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Abstract

Red-colored crystalline gold complexes [p-Tol4Sb][Au(CN)2I2] (I), [Ph3PMe][Au(CN)2I2] (II), and [Ph3PCH2CN][Au(CN)2I2] (III) were synthesized by the reaction of potassium dicyanodiiodoaurate with tetra(para-tolyl)antimony and alkyltriphenylphosphonium halides in water. The structure of the complexes was established by IR and NMR spectroscopy and X-ray diffraction. The tetra(para-tolyl)antimony and alkyltriphenylphosphonium cations have a distorted tetrahedral coordination. The dicyanodiiodoaurate anions have a planar structure with a square coordination of the gold atom. The formation of the 3D crystal network is due to weak CN⋅⋅⋅H−C hydrogen bonds between cations and anions (2.39, 2.59 Å (I), 2.70, 2.48, 2.52, 2.68 Å (II), 2.73, 2.50, 2.67, 2.44 Å (III)). In complex III, anions of one of the two types interact with one another via I⋅⋅⋅I contacts to give 1D ladder-like chains along the crystallographic a axis.

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REFERENCES

  1. Xiaobo, L. and Patterson, H., Materials, 2013, vol. 6, p. 2595. https://doi.org/10.3390/ma6072595

    Article  CAS  Google Scholar 

  2. Dechambenoit, P., Ferlay, S., Kyritsakas, N., et al., CrystEngComm, 2011, vol. 13, p. 1922. https://doi.org/10.1039/C0CE00607F

    Article  CAS  Google Scholar 

  3. Hill, J.A., Thompson, A.L., and Goodwin, A.L., J. Am. Chem. Soc., 2018, vol. 138, p. 5886. https://doi.org/10.1021/jacs.5b13446

    Article  CAS  Google Scholar 

  4. Assefa, Z., Haire, R.G., and Sykora, R.E., J. Solid State Chem., 2008, vol. 181, p. 382. https://doi.org/10.1016/j.jssc.2007.11.036

    Article  CAS  Google Scholar 

  5. Brown, M.L., Ovens, J.S., and Leznoff, D.B., Dalton Trans., 2017, vol. 46, p. 7169. https://doi.org/10.1039/C7DT00942A

    Article  CAS  PubMed  Google Scholar 

  6. Chorazy, S., Wyczesany, M., and Sieklucka, B., Molecules, 2017, vol. 22, p. 1902. https://doi.org/10.3390/molecules22111902

    Article  CAS  PubMed Central  Google Scholar 

  7. Shaw, C.F., Chem. Rev., 1999, vol. 99, no. 9, p. 2589. https://doi.org/10.1021/cr980431o

    Article  CAS  Google Scholar 

  8. Roberts, R.J., Le, D., and Leznoff, D.B., Inorg. Chem., 2017, vol. 56, no. 14, p. 7948. https://doi.org/10.1021/acs.inorgchem.7b00735

    Article  CAS  PubMed  Google Scholar 

  9. Rawashdeh-Omary, M.A., Omary, M.A., Shankle, G.E., et al., J. Phys. Chem. B, 2000, vol. 104, no. 26, p. 6143. https://doi.org/10.1021/jp000563x

    Article  CAS  Google Scholar 

  10. Colis, J.C.F., Larochelle, C., Fernández, E.J., et al., J. Phys. Chem. B, 2005, vol. 109, no. 10, p. 4317. https://doi.org/10.1021/jp045868g

    Article  CAS  PubMed  Google Scholar 

  11. Assefa, Z., Kalachnikova, K., Hairec, R.G., et al., J. Solid State Chem., 2007, vol. 180, p. 3121. https://doi.org/10.1016/j.jssc.2007.08.032

    Article  CAS  Google Scholar 

  12. Ovens, J.S. and Leznoff, D.B., Chem. Mater., 2015, vol. 27, no. 5, p. 1465. https://doi.org/10.1021/cm502998w

    Article  CAS  Google Scholar 

  13. Ovens, J.S. and Leznoff, D.B., Dalton Trans., 2011, p. 4140. https://doi.org/10.1039/c0dt01772h

  14. Sharutin, V.V., Popkova, M.A., and Tarasova, N.M., Bull. South Ural State Univ.,Ser. Chem., 2018, vol. 10, no. 1, p. 55. https://doi.org/10.14529/chem180107

    Article  Google Scholar 

  15. Sharutin, V.V., Sharutina, O.K., and Popkova, M.A., Russ. J. Inorg. Chem., 2019, vol. 64, no. 6, p. 607. https://doi.org/10.1134/S0036023619060147

    Article  Google Scholar 

  16. Cambridge Crystallographic Data Center, 2018. http://www.ccdc.cam.ac.uk.

  17. Ovens, J.S., Geisheimer, A.R., Bokov, A.A., et al., Inorg. Chem., 2010, vol. 49, p. 9609. https://doi.org/10.1021/ic101357y

    Article  CAS  PubMed  Google Scholar 

  18. Pitteri, B., Bortoluzzi, M., and Bertolasi, V., Transition Met.Chem., 2008, vol. 33, p. 649. https://doi.org/10.1007/s11243-008-9092-9

    Article  CAS  Google Scholar 

  19. Marangoni, G., Pitteri, B., Bertolasi, V., et al., Dalton Trans., 1987, no. 1, p. 2235. https://doi.org/10.1039/DT9870002235

  20. Ovens, J.S., Truong, K.N., and Leznoff, D.B., Dalton Trans., 2012, vol. 41, p. 1345. https://doi.org/10.1039/c1dt11741f

    Article  CAS  PubMed  Google Scholar 

  21. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System, Madison: Bruker AXS Inc., 1998.

  22. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Madison: Bruker AXS Inc., 1998.

  23. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339. https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  24. Pretsch, E., Bühlmann, F., and Affolter, C., Structure Determination of Organic Compounds, Berlin: Springer, 2000.

    Book  Google Scholar 

  25. Batsanov, S.S., Russ. J. Inorg. Chem., 1991, vol. 3, p. 1694.

    Google Scholar 

  26. Mukherjee, A., Tothadi, S., and Desiraju, G.R., Acc. Chem. Res., 2014, vol. 47, no. 8, p. 2514. https://doi.org/10.1021/ar5001555

    Article  CAS  PubMed  Google Scholar 

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Funding

This study was supported by the Ministry of Education and Science of the Russian Federation (grant no. 4.6151.2017/8.9).

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Authors and Affiliations

  1. National South Ural State Research University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

  2. Ural Federal University Named after the First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia

    O. S. Eltsov

Authors
  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. N. Efremov
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  4. O. S. Eltsov
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Correspondence to A. N. Efremov.

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Translated by Z. Svitanko

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Sharutin, V.V., Sharutina, O.K., Efremov, A.N. et al. Synthesis and Structure of Tetra(para-tolyl)antimony Dicyanodiiodoaurate [p-Tol4Sb][Au(CN)2I2] and Alkyltriphenylphosphonium Dicyanodiiodoaurates [Ph3PAlk][Au(CN)2I2], Alk = Me, CH2CN. Russ J Coord Chem 46, 631–638 (2020). https://doi.org/10.1134/S1070328420090031

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