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Heteroleptic Binuclear Iodoacetate Copper(II) Complexes with 3-Bromopyridine and 4-Ethylpyridine: Crystal Structures and Peculiarities of Contacts Halogen···Halogen

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Abstract

The reactions of [Cu2(IOAc)4(H2O)2] with 3-bromopyridine and 4-ethylpyridine in acetone afford heteroligand complexes [Cu2(IOAc)4(3-BrPy)2] (I) and [Cu2(IOAc)4(4-EtPy)2] (II). Their structures are determined by X-ray diffraction analysis (CIF files CCDC nos. 1945900 (I) and 1945901 (II)). Specific noncovalent interactions I···I and Br···I leading to the formation of supramolecular polymers are observed in the crystal structure of complex I. The energies of the contacts are determined using quantum chemical methods.

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Funding

The experimental part of the work was supported by the Russian Foundation for Basic Research, project no. 19-43-540005. The theoretical part of the work was carried out by A.S. Novikov and supported by the Russian Science Foundation, project no. 19-73-00001.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    S. A. Adonin & V. P. Fedin

  2. Tyumen Industrial University, Tobolsk Industrial Institute (Branch), Tobolsk, Russia

    S. A. Adonin

  3. Southern Ural State University, Chelyabinsk, Russia

    S. A. Adonin

  4. Novosibirsk National Research University, 630090, Novosibirsk, Russia

    S. A. Adonin & V. P. Fedin

  5. St. Petersburg State University, 199164, St. Petersburg, Russia

    A. S. Novikov

Authors
  1. S. A. Adonin
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  2. A. S. Novikov
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  3. V. P. Fedin
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Correspondence to S. A. Adonin.

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Translated by E. Yablonskaya

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Adonin, S.A., Novikov, A.S. & Fedin, V.P. Heteroleptic Binuclear Iodoacetate Copper(II) Complexes with 3-Bromopyridine and 4-Ethylpyridine: Crystal Structures and Peculiarities of Contacts Halogen···Halogen. Russ J Coord Chem 46, 119–124 (2020). https://doi.org/10.1134/S1070328420020013

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