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Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties

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Abstract

The binuclear oxidovanadium(IV) complex [VO(Dbbpy)Cl(Ca)Cl(Dbbpy)VO] (I) is synthesized by the reaction of [VO(Dbbpy)(H2O)Cl2] (Dbbpy is 4,4'-di-tert-butyl-2,2'-bipyridyl) with chloranilic acid H2Ca in acetonitrile in the presence of Et3N in a yield of 79%. Complex I is reduced at Е1/2 = –842 mV (vs. Ag/AgCl), which is shown by cyclic voltammetry for a solid sample using the paste electrode. The EPR spectra and magnetochemical measurements for complex I confirm the existence of two paramagnetic vanadium(IV) centers with the total spin S = 1 and the antiferromagnetic character of the exchange interaction between the centers.

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REFERENCES

  1. Galloni, P. and Floris, B., Coord. Chem., 2015, vols. 301–302, p. 240.

    Article  CAS  Google Scholar 

  2. Sutradhar, M., Martins, L.M.D.R.S., Guedes da Silva, M.F.C., and Pombeiro, A.J.L., Coord. Chem. Rev., 2015, vols. 301–302, p. 200.

    Article  CAS  Google Scholar 

  3. Langeslay, R.R., Kaphan, D.M., Marshall, C.L., et al., Chem. Rev., 2019, vol. 119, no. 4, p. 2128.

    Article  CAS  PubMed  Google Scholar 

  4. Nomura, K. and Zhang, S., Chem. Rev., 2011, vol. 111, no. 3, p. 2342.

    Article  CAS  PubMed  Google Scholar 

  5. Wischang, D., Brucher, O., and Hartung, J., Coord. Chem. Rev., 2011, vol. 255, nos. 19–20, p. 2204.

    Article  CAS  Google Scholar 

  6. Butler, A. and Carter-Franklin, J.N., Nat. Prod. Rep., 2004, vol. 21, no. 1, p. 180.

    Article  CAS  PubMed  Google Scholar 

  7. Butler, A., Coord. Chem. Rev., 1999, vol. 187, no. 1, p. 17.

    Article  CAS  Google Scholar 

  8. Rehder, D., Santoni, G., Licini, G.M., et al., Coord. Chem. Rev., 2003, vol. 237, nos. 1–2, p. 53.

    Article  CAS  Google Scholar 

  9. Rehder, D., Bioinorganic Vanadium Chemistry, New York: Wiley, 2008.

    Book  Google Scholar 

  10. Hales, B.J., Case, E.E., Morningstar, J.E., et al., Biochemistry, 1986, vol. 25, no. 23, p. 7251.

    Article  CAS  PubMed  Google Scholar 

  11. Robson, R.L., Robson, R.L., Eady, R.R., et al., Nature, 1986, vol. 322, no. 6077, p. 388.

    Article  CAS  Google Scholar 

  12. Shul’pin, G.B., Mishra, G.S., Shul’pina, L.S., et al., Catal. Commun., 2007, vol. 8, no. 10, p. 1516.

    Article  CAS  Google Scholar 

  13. Romakh, V.B., Süss-Fink, G., and Shul’pin, G.B., Pet. Chem., 2008, vol. 48, no. 6, p. 440.

    Article  Google Scholar 

  14. Shul’pina, L.S., Kirillova, M.V., Pombeiro, A.J.L., and Shul’pin, G.B., Tetrahedron, 2009, vol. 65, no. 12, p. 2424.

    Article  CAS  Google Scholar 

  15. Kirillova, M.V., Kuznetsov, M.L., Romakh, V.B., et al., J. Catal., 2009, vol. 267, no. 2, p. 140.

    Article  CAS  Google Scholar 

  16. Kirillova, M.V., Kuznetsov, M.L., Kozlov, Y.N., et al., ACS Catal., 2011, vol. 1, no. 11, p. 1511.

    Article  CAS  Google Scholar 

  17. Gusevskaya, E.V., Menini, L., Parreira, L.A., et al., J. Mol. Catal. A, 2012, vols. 363–364, p. 140.

    Article  CAS  Google Scholar 

  18. Sutradhar, M., Shvydkiy, N.V., Guedes da Silva, M.F.C., et al., Dalton Trans., 2013, vol. 42, no. 33, p. 11791.

    Article  CAS  PubMed  Google Scholar 

  19. Gryca, I., Czerwin'ska, K., Machura, B., et al., Inorg. Chem., 2018, vol. 57, no. 4, p. 1824.

    Article  CAS  PubMed  Google Scholar 

  20. Brücher, O. and Hartung, J., ACS Catal., 2011, vol. 1, no. 11, p. 1448.

    Article  CAS  Google Scholar 

  21. Kikushima, K., Moriuchi, T., and Hirao, T., Tetrahedron, 2010, vol. 66, no. 34, p. 6906.

    Article  CAS  Google Scholar 

  22. Maurya, M.R., Chaudhary, N., and Avecilla, F., Polyhedron, 2014, vol. 67, p. 436.

    Article  CAS  Google Scholar 

  23. Galloni, P., Mancini, M., Floris, B., and Conte, V., Dalton Trans., 2013, vol. 42, no. 33, p. 11963.

    Article  CAS  PubMed  Google Scholar 

  24. Grivani, G., Tahmasebi, V., and Khalaji, A.D., Polyhedron, 2014, vol. 68, p. 144.

    Article  CAS  Google Scholar 

  25. Zhang, R., Liu, J., Chen, C., et al., Spectrochim. Acta, Part A, 2013, vol. 115, p. 476.

    Article  CAS  Google Scholar 

  26. Hall, N., Orio, M., Jorge-Robin, A., et al., Inorg. Chem., 2013, vol. 52, no. 23, p. 13424.

    Article  CAS  PubMed  Google Scholar 

  27. Barman, S., Patil, S., Desper, J., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, no. 33, p. 5708.

    Article  CAS  Google Scholar 

  28. Maurya, M.R., Bisht, M., Chaudhary, N., et al., Polyhedron, 2013, vol. 54, p. 180.

    Article  CAS  Google Scholar 

  29. Maurya, M.R., Bisht, M., and Avecilla, F., J. Mol. Catal. A: Chem., 2011, vol. 344, nos. 1–2, p. 18.

    Article  CAS  Google Scholar 

  30. Romanowski, G. and Kira, J., Polyhedron, 2013, vol. 53, p. 172.

    Article  CAS  Google Scholar 

  31. Maurya, M.R., Saini, P., Kumar, A., and Costa Pessoa, J., Eur. J. Inorg. Chem., 2011, vol. 2011, no. 31, p. 4846.

    Article  CAS  Google Scholar 

  32. Jin, W.-T., Weng, W.-Z., and Zhou, Z.-H., Eur. J. Inorg. Chem., 2019, vol. 2019, no. 9, p. 1228.

    Article  CAS  Google Scholar 

  33. Zeng, Q., Gao, Y., Dong, J., et al., Tetrahedron: Asymmetry, 2011, vol. 22, no. 7, p. 717.

    Article  CAS  Google Scholar 

  34. Maurya, M.R., Arya, A., Kumar, A., et al., Inorg. Chem., 2010, vol. 49, no. 14, p. 6586.

    Article  CAS  PubMed  Google Scholar 

  35. Ogunlaja, A.S., Chidawanyika, W., Antunes, E., et al., Dalton Trans., 2012, vol. 41, no. 45, p. 13908.

    Article  CAS  PubMed  Google Scholar 

  36. Wu, Y., Mao, F., Meng, F., and Li, X., Adv. Synth. Catal., 2011, vol. 353, no. 10, p. 1707.

    Article  CAS  Google Scholar 

  37. Walmsley, R.S., Chigome, S., Torto, N., and Tshentu, Z.R., Catal. Lett., 2012, vol. 142, no. 2, p. 243.

    Article  CAS  Google Scholar 

  38. Stingl, K.A., Weiss, K.M., and Tsogoeva, S.B., Tetrahedron, 2012, vol. 68, no. 40, p. 8493.

    Article  CAS  Google Scholar 

  39. Romanowski, G. and Lis, T., Inorg. Chim. Acta, 2013, vol. 394, p. 627.

    Article  CAS  Google Scholar 

  40. Barroso, S., Adão, P., Madeira, F., et al., Inorg. Chem., 2010, vol. 49, no. 16, p. 7452.

    Article  CAS  PubMed  Google Scholar 

  41. Pessoa, J.C., Etcheverry, S., and Gambino, D., Coord. Chem. Rev., 2015, vols. 301–302, p. 24.

    Article  CAS  Google Scholar 

  42. Kioseoglou, E., Petanidis, S., Gabriel, C., and Salifoglou, A., Coord. Chem. Rev., 2015, vols. 301–302, p. 87.

    Article  CAS  Google Scholar 

  43. Fomenko, Y.S., Gushchin, A.L., Tkachev, A.V., et al., Polyhedron, 2017, vol. 135, p. 96.

    Article  CAS  Google Scholar 

  44. Fomenko, I.S., Gushchin, A.L., Shul’pina, L.S., et al., New J. Chem., 2018, vol. 42, no. 19, p. 16200.

    Article  CAS  Google Scholar 

  45. Chatterjee, P.B., Bhattacharya, K., Kundu, N., et al., Inorg. Chem., 2009, vol. 48, no. 3, p. 804.

    Article  CAS  PubMed  Google Scholar 

  46. Bazhina, E.S., Nikiforova, M.E., Aleksandrov, G.G., et al., Inorg. Chim. Acta, 2012, vol. 392, p. 192.

    Article  CAS  Google Scholar 

  47. Bazhina, E.S., Aleksandrov, G.G., Kiskin, M.A., et al., Polyhedron, 2017, vol. 137, p. 246.

    Article  CAS  Google Scholar 

  48. Moreno, Y., Vega, A., Ushak, S., et al., J. Mater. Chem., 2003, vol. 13, no. 9, p. 2381.

    Article  CAS  Google Scholar 

  49. Marino, N., Lloret, F., Julve, M., and Doyle, R.P., Dalton Trans., 2011, vol. 40, no. 45, p. 12248.

    Article  CAS  PubMed  Google Scholar 

  50. Zhimin, D., Zhan, S., Guanghua, L., et al., Inorg. Chem., 2003, vol. 42, p. 7396.

    Article  CAS  Google Scholar 

  51. Kawasaki, S., Koikawa, M., and Tokii, T., Mol. Cryst. Liq. Cryst., 2002, vol. 376, no. 1, p. 365.

    Article  CAS  Google Scholar 

  52. Matsuoka, N., Kawamura, H., and Yoshioka, N., Chem. Phys. Lett., 2010, vol. 488, nos. 1–3, p. 32.

    Article  CAS  Google Scholar 

  53. Drake, R.F., Crawford, V.H., Hatfield, W.E., et al., J. Inorg. Nucl. Chem., 1975, vol. 37, no. 1, p. 291.

    Article  CAS  Google Scholar 

  54. Tsuchimoto, M. and Yoshioka, N., Chem. Phys. Lett., 1998, vol. 287, p. 115.

    Article  Google Scholar 

  55. Rodríguez-Fortea, A., Alemany, P., Alvarez, S., and Ruiz, E., Eur. J. Inorg. Chem., 2004, vol. 2004, no. 1, p. 143.

    Article  CAS  Google Scholar 

  56. Plass, W., Angew. Chem., Int. Ed. Engl., 1996, vol. 35, no. 6, p. 627.

    Article  CAS  Google Scholar 

  57. Zakharchuk, N.F., Meyer, B., Henning, H., et al., J. Electroanal. Chem., 1995, vol. 398, nos. 1–2, p. 23.

    Article  Google Scholar 

  58. Fomenko, I., Gushchin, A., Abramov, P., et al., Catalysts, 2019, vol. 9, no. 3, p. 217.

    Article  CAS  Google Scholar 

  59. Min, K.S., DiPasquale, A., Rheingold, A.L., and Miller, J.S., Inorg. Chem., 2007, vol. 46, no. 4, p. 1048.

    Article  CAS  PubMed  Google Scholar 

  60. Guo, D. and McCusker, J.K., Inorg. Chem., 2007, vol. 46, no. 8, p. 3257.

    Article  CAS  PubMed  Google Scholar 

  61. Min, K.S., Rheingold, A.L., DiPasquale, A., and Miller, J.S., Inorg. Chem., 2006, vol. 45, no. 16, p. 6135.

    Article  CAS  PubMed  Google Scholar 

  62. Kitagawa, S. and Kawata, S., Coord. Chem. Rev., 2002, vol. 224, nos. 1–2, p. 11.

    Article  CAS  Google Scholar 

  63. Min, K.S., DiPasquale, A.G., Golen, J.A., et al., J. Am. Chem. Soc., 2007, vol. 129, no. 8, p. 2360.

    Article  CAS  PubMed  Google Scholar 

  64. Gushchin, A.L., Laricheva, Y.A., Abramov, P.A., et al., Eur. J. Inorg. Chem., 2014, vol. 2014, no. 25, p. 4093.

    Article  CAS  Google Scholar 

  65. Kaim, W., Inorg. Chem., 2011, vol. 50, no. 20, p. 9752.

    Article  CAS  PubMed  Google Scholar 

  66. Kaim, W. and Schwederski, B., Coord. Chem. Rev., 2010, vol. 254, nos. 13–14, p. 1580.

    Article  CAS  Google Scholar 

  67. Gushchin, A.L., Sokolov, M.N., Peresypkina, E.V., et al., Eur. J. Inorg. Chem., 2008, vol. 2008, no. 25, p. 3964.

    Article  CAS  Google Scholar 

  68. Gushchin, A.L., Laricheva, Y.A., Piryazev, D.A., and Sokolov, M.N., Russ. J. Coord. Chem., 2014, vol. 40, no. 1, p. 5.https://doi.org/10.1134/S1070328414010023

    Article  CAS  Google Scholar 

  69. Zhu, H., Chen, C., Zhang, X., et al., Inorg. Chim. Acta, 2002, vol. 328, no. 1, p. 96.

    Article  CAS  Google Scholar 

  70. Hongping, Z., Liu, Q., Xiaoying, H., et al., Inorg. Chem. A, 1998, vol. 37, no. 11, p. 2678.

    Article  Google Scholar 

  71. Chilton, N.F., Anderson, R.P., Turner, L.D., et al., J. Comput. Chem., 2013, vol. 34, no. 13, p. 1164.

    Article  CAS  PubMed  Google Scholar 

  72. Apostolopoulou, A., Vlasiou, M., Tziouris, P.A., et al., Inorg. Chem., 2015, vol. 54, no. 8, p. 3979.

    Article  CAS  PubMed  Google Scholar 

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Funding

The works on the synthesis and characterization of compound I were supported by the Russian Foundation for Basic Research, project no. 18-03-00155. The study of the magnetic properties was supported by the Russian Science Foundation, project no. 16-13-10407.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. S. Fomenko, V. A. Nadolinnyi, V. V. Kokovkin & A. L. Gushchin

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    N. N. Efimov

  3. Novosibirsk National Research State University, 630090, Novosibirsk, Russia

    V. V. Kokovkin & A. L. Gushchin

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  1. I. S. Fomenko
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  2. V. A. Nadolinnyi
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  3. N. N. Efimov
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  4. V. V. Kokovkin
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  5. A. L. Gushchin
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Correspondence to A. L. Gushchin.

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Translated by E. Yablonskaya

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Fomenko, I.S., Nadolinnyi, V.A., Efimov, N.N. et al. Binuclear Oxidovanadium(IV) Complex with the Bridging Chloranilate Ligand: Synthesis and Magnetic Properties. Russ J Coord Chem 45, 776–781 (2019). https://doi.org/10.1134/S1070328419110022

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  • DOI: https://doi.org/10.1134/S1070328419110022

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