Skip to main content
SpringerLink
Log in

Two Novel Supramolecules Built by Dimethylphenyl Imidazole Dicarboxylate: Syntheses, Structures, and Thermal Properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

By solvothermal reactions of ZnSO4 ⋅ 7H2O and NiSO4 ⋅ 6H2O with 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid (3,4-DMPhH3IDC), respectively, two supramolecular complexes, [Zn(3,4-DMPhHIDC)2(H2O)2]n (I) and [Ni(3,4-DMPhHIDC)2(H2O)2]n (II) have been successfully prepared and structurally characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1440305 (I) and 1440316 (II)), elemental analyses, and IR spectroscopy. The results show that ligand 3,4-DMPhH3IDC in the two complexes has quite strong coordination ability, and the 3D solid-state supramolecular structures of I and II involve intermolecular hydrogen bonds. The thermal properties of the complexes have also been investigated and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Sadhu, B., Sundararajan, M., and Bandyopadhyay, T., Inorg. Chem., 2016, vol. 55, p. 598.

    Article  CAS  PubMed  Google Scholar 

  2. Horiuchi, S., Kumai. R., and Tokura. Y., J. Am. Chem. Soc., 2013, vol. 135, p. 4492.

    Article  CAS  PubMed  Google Scholar 

  3. Liang, X., Li, B., and Wang, M.H., ACS Appl. Mater. Interfaces, 2017, vol. 9, p. 25082.

    Article  CAS  PubMed  Google Scholar 

  4. Chen, S.P., Hu. L., Hu, X.J., et al., Cryst. Growth Des., 2009, vol. 9, p. 3835.

    Article  CAS  Google Scholar 

  5. Zhong, D.C. and Lu, T.B., Sci. Chin. Chem., 2011, vol. 54, p. 1395.

    Article  CAS  Google Scholar 

  6. Zhou, W.Y., Zhao, L.J., An, Z.L., et al., Polyhedron, 2016, vol. 117, p. 202.

    Article  CAS  Google Scholar 

  7. Liang, X., Wang, J., Wang, Q., et al., Supramol. Chem., 2017, vol. 29, p. 237.

    Article  CAS  Google Scholar 

  8. Liu, R.L., Zhao, L.L., Dai, W., et al., Inorg. Chem., 2018, vol. 57, p. 1474.

    Article  CAS  PubMed  Google Scholar 

  9. Lu, W.G., Jiang, L., and Lu, T.B., Cryst. Growth Des., 2010, vol. 10, p. 4310.

    Article  CAS  Google Scholar 

  10. Xiong, Z.F., Gao, R.M., Xie, Z.K., et al., Dalton. Trans., 2013, vol. 42, p. 4613.

    Article  CAS  PubMed  Google Scholar 

  11. Zhang, Y., Guo, B.B., Li, L., et al., Cryst. Growth Des., 2013, vol. 13, p. 367.

    Article  CAS  Google Scholar 

  12. Wang, C.J., Wang, T., Li, L., et al., Dalton Trans., 2013, vol. 42, p. 1715.

    Article  CAS  PubMed  Google Scholar 

  13. Guo, M.W., Chen, N., Yue, Z.F., et al., CrystEngComm, 2012, vol. 14, p. 4955.

    Article  CAS  Google Scholar 

  14. Wang, W.Y., Yang, Z.L., Wang, C.J., et al., CrystEngComm, 2011, vol. 13, p. 4895.

    Article  CAS  Google Scholar 

  15. Grimmett, M.R., Org. Chem., 2002, vol. 12, p. 325.

    CAS  Google Scholar 

  16. Sheldrick, G.M., SHELXTL, Version 5.1, Software Reference Manual, Madison: Bruker AXS, Inc., 1997.

    Google Scholar 

  17. Yang, Q., Song, X.X., Ge, J., et al., J. Chem. Therm., 2016, vol. 92, p. 132.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Chifeng University, 024000, Chifeng, Neimenggu, P.R. China

    X. S. Lin & Y. L. Sang

Authors
  1. X. S. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. L. Sang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. L. Sang.

Additional information

1The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lin, X.S., Sang, Y.L. Two Novel Supramolecules Built by Dimethylphenyl Imidazole Dicarboxylate: Syntheses, Structures, and Thermal Properties. Russ J Coord Chem 44, 533–539 (2018). https://doi.org/10.1134/S1070328418090051

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328418090051

Keywords:

Search

Navigation