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Syntheses, Structures, and Properties of Two Zn(II)/Ag(I) Complexes Assembled from Tetracarboxylic Acids and N-Donor Ligands

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Abstract

Two new complexes {[Zn(H2L)(Bpp)] · H2O} n (I) and {[Ag(H3L)(Bpp)] · 0.25H2O} n (II) (H4L = 5-(2,3-dicarboxy phenoxy) isophthalic acid, Bpp = 1,3-bis(4-pyridyl)propane) were prepared and characterized by single crystal X-ray diffraction (XRD) (CCDC nos. 1578523 (I), 1578529 (II)), element analysis and powder XRD. Compound I showed a one-dimensional chain structure, in which the zinc(II) ion is fourcoordinated with a tetrahedral geometry. Compound II is a 1D chain structure with the H3L– suspension arms. Complexes I and II are further extended into three-dimensional supramolecular framework via hydrogen bonds and π–π interactions. The solid state luminescent properties of compounds I and II have been investigated.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, 471934, P.R. China

    Y. P. Li, G. L. Li, L. Y. Xin, X. L. Li & G. Z. Liu

  2. School of Food and Drug, Luoyang Normal University, Luoyang, 471934, P.R. China

    F. Y. Ju

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  1. Y. P. Li
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  2. F. Y. Ju
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  3. G. L. Li
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  4. L. Y. Xin
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  5. X. L. Li
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  6. G. Z. Liu
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Correspondence to G. Z. Liu.

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Li, Y.P., Ju, F.Y., Li, G.L. et al. Syntheses, Structures, and Properties of Two Zn(II)/Ag(I) Complexes Assembled from Tetracarboxylic Acids and N-Donor Ligands. Russ J Coord Chem 44, 214–219 (2018). https://doi.org/10.1134/S1070328418030028

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  • DOI: https://doi.org/10.1134/S1070328418030028

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