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Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} · 4H2O

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Abstract

A new compound {[Cu(En)2]2V2O7} · 4H2O (I) (En = ethanediamine) has been synthesized by the combination of hydrothermal and solvent evaporation method and characterized by single-crystal X-ray diffraction (CIF file CCDC no. 1450218), IR, UV-Vis spectra, thermogravimetric analysis, powder X-ray diffraction, and fluorescence analysis. Crystal data for I: C8H40Cu2N8O11V2, Mr = 653.44, orthorhombic, space group Cmca, a = 18.559(11), b = 17.583(11), c = 7.600(6) Å, V = 2480(3) Å3, and Z = 4. Interestingly, two [Cu(En)2]2+ coordination cations are bridged by the [V2O7]4– unit to build up a neutral framework compound.

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Authors and Affiliations

  1. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, P.R. China

    K. Wang, J. Li, Z. J. Liang, P. T. Ma, D. D. Zhang, J. Y. Niu & J. P. Wang

  2. Department of Pharmacy, Henan Medical College, Zhengzhou, 451191, P.R. China

    K. Wang

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  1. K. Wang
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  2. J. Li
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  3. Z. J. Liang
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  4. P. T. Ma
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  5. D. D. Zhang
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  6. J. Y. Niu
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  7. J. P. Wang
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Correspondence to K. Wang.

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Wang, K., Li, J., Liang, Z.J. et al. Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} · 4H2O. Russ J Coord Chem 43, 795–799 (2017). https://doi.org/10.1134/S1070328417110112

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  • DOI: https://doi.org/10.1134/S1070328417110112

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