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Synthesis, spectral characterization, and electrochemical property of Cu(II) complex with 1,2-phenylenedioxydiacetic acid and 1,10-phenanthroline

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Abstract

A novel dinuclear Cu(II) complex, [Cu2L(phen)4]·L [H2L = 1,2-phenylenedioxydiacetic acid], was obtained by the self-assembly of 1,2-phenylenedioxydiacetic acid, phen and Cu(CH3COO)2·H2O in CH3OH/H2O (v:v = 1:1) solution containing MgCl2. The Cu(II) complex has been characterized by elemental analysis, IR, UV, and X-ray single-crystal diffraction analysis. The crystal belongs to triclinic, space group P − 1 with a = 13.090(3) Å, b = 14.211(3) Å, c = 19.255(4) Å, α = 92.91(3)°, β = 91.29(3)°, γ = 110.01(3)°, V = 3,358.2(13) Å3, Z = 2, D c = 1.282 g cm−3, μ = 0.698 mm−1, F (000) = 1,332, and final R = 0.0744, ωR = 0.2109. In the crystal structure, each Cu(II) atom is five-coordinated in a distorted square pyramid coordination environment. The molecules form one-dimensional chain structure by π–π stack. The electrochemical properties of the Cu(II) complex have been investigated.

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References

  1. Z.F. Xiong, P.F. Yuan, Z.K. Xie, G. Li, Supramol. Chem. 26, 346 (2014)

    Article  CAS  Google Scholar 

  2. H. Liu, G.S. Yang, C.B. Liu, Y. Lin, Y. Yang, Y.N. Gong, J. Coord. Chem. 67, 572 (2014)

    Article  CAS  Google Scholar 

  3. X.K. Yu, W.D. Weng, X.X. Guo, Y.Q. Zheng, J. Inorg. Organomet. Polym. 23, 1451 (2013)

    Article  CAS  Google Scholar 

  4. T.F. Yan, M. Hong, L. Niu, F. Jiang, G.M. Xiao, Res. Chem. Intermed. 38, 1389 (2012)

    Article  Google Scholar 

  5. D.T. Shi, B. Zhang, Y.X. Yang, C.C. Guan, X.P. He, Y.C. Li, G.R. Chen, K.X. Chen, Analyst 138, 2808 (2013)

    Article  CAS  Google Scholar 

  6. X.S. Tai, J.H. Jiang, Materials 5, 1626 (2012)

    Article  CAS  Google Scholar 

  7. L.J. Li, C. Wang, Y. Qiao, X.Y. Yang, X.X. Hua, J.L. Du, Res. Chem. Intermed. 40, 413 (2014)

    Article  CAS  Google Scholar 

  8. J.G. Małecki, S. Krompiec, A. Maroń, M. Penkala, Polyhedron 48, 21 (2012)

    Article  Google Scholar 

  9. X.S. Tai, W.H. Zhao, F.H. Li, Chin. J. Inorg. Chem. 29, 1328 (2013)

    CAS  Google Scholar 

  10. P.K. Yata, M. Shilpa, P. Nagababu, M.R. Reddy, L.R. Kotha, N.M. Gabr, S. Satyanarayana, J. Fluoresc. 22, 835 (2012)

    Article  CAS  Google Scholar 

  11. Y.A. Bryleva, L.A. Glinskaya, I.V. Korol’kov, A.S. Bogomyakov, M.I. Rakhmanova, D.Y. Naumov, T.E. Kokina, S.V. Larionov, J. Struct. Chem. 55, 319 (2014)

    Article  CAS  Google Scholar 

  12. C. Rajarajeswari, M. Ganeshpandian, M. Palaniandavar, A. Riyasdeen, M.A. Akbarsha, J. Inorg. Biochem. 140C, 255 (2014)

    Article  Google Scholar 

  13. F. Arjmand, S. Parveen, M. Afzal, L. Toupet, H.T. Ben, Eur. J. Med. Chem. 49C, 141 (2012)

    Article  Google Scholar 

  14. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  15. G.M. Sheldrick, SHELXTL-97, Program for Crystal Structure Refinement (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  16. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd edn. (Wiley, New York, 1978)

    Google Scholar 

  17. X.S. Tai, L.L. Liu, J. Yin, J. Inorg. Organomet. Polym. 24, 1014 (2014)

    Article  CAS  Google Scholar 

  18. S. Kashanian, M.M. Khodaei, H. Roshanfekr, G. Mansouri, Mol. Biol. Rep. 41, 25 (2014)

    Article  CAS  Google Scholar 

  19. Y.H. Tang, Y. Qu, Z. Song, X.P. He, J. Xie, J.L. Hua, G.R. Chen, Org. Biomol. Chem. 10, 555 (2012)

    Article  CAS  Google Scholar 

  20. Y.J. Zhang, X.P. He, M. Hu, Z. Li, X.X. Shi, G.R. Chen, Dyes Pigm. 88, 391 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to thank the National Natural Science Foundation of China (No. 21171132), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01) and Science Foundation of Weifang.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Weifang University, Weifang, 261061, People’s Republic of China

    Xi-Shi Tai & Li Liu

  2. College of Applied Chemistry and Environmental Engineering, Xinyang Vocational and Technical College, Xinyang, 464000, People’s Republic of China

    Jie Yin

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  1. Xi-Shi Tai
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  2. Li Liu
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Correspondence to Xi-Shi Tai.

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Tai, XS., Liu, L. & Yin, J. Synthesis, spectral characterization, and electrochemical property of Cu(II) complex with 1,2-phenylenedioxydiacetic acid and 1,10-phenanthroline. Res Chem Intermed 41, 8279–8287 (2015). https://doi.org/10.1007/s11164-014-1891-3

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