Skip to main content
SpringerLink
Log in

New metal complex systems as electrode active components of ion selective electrode membranes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

New donor-acceptor 3d-transition metal complexes were synthesized and the cobalt and nickel complexes were studied by X-ray diffraction; CIF files CCDC no. 1516693 (III(Ni)) and 1516694 (III(Co)). The crystal structure details of the reactants were discussed. The proposed compounds were tested as the active components of ion selective electrode membranes for determination of thiocyanate ions. The selectivity of the SCN-SE with metal complex-based membranes depends on the ligand structure and the central metal ion type. The proposed electrode is suitable for determination of thiocyanate ions in the presence of sulfate, chloride, nitrate, nitrite, bromide, and iodide ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Il’ina, I.G. and Mikhalev, O.V., Russ. J. Org. Chem., 2011, vol. 47. no. 10, p. 1515.

    Article  Google Scholar 

  2. Grandberg, K.I., Kuz’mina, L.G., Aleksandrov, G.G., et al., Chemistry of Heterocyclic Compounds, 1999, vol. 35, no. 8, p. 900.

    Article  CAS  Google Scholar 

  3. Mikhalev, O.V., Fedyanin, I.V., Tarasevich, B.N., et al., Vestn. Mosk. un-ta. Ser. 2. Khim., 2007, vol. 48. no. 2, p.118.

    CAS  Google Scholar 

  4. Il’ina, I.G., Tarasevich, B.N., Fedyanin, I.V., and Mikhalev, O.V., in Nitrogen-Containing Heterocycles, Kartsev, V.G., Ed., Moscow: ICSPF, 2006, vol. 1, p. 355.

    Google Scholar 

  5. Il’ina, I.G., Mikhalev, O.V., Butin, K.P., and Ashkinadze, L.D., Russ. J. Org. Chem., 2003, vol. 39, no. 1, p. 99.

    Article  Google Scholar 

  6. Butin, K.P., Il’ina, I.G., Magdesieva, T.V., et al., Inform. Byul. RFFI, 1997, vol. 5, ser. 4, p.208.

    Google Scholar 

  7. Leininger, S., Olenyuk, B., and Stang, P.J., Chem. Rev., 2000, vol. 100, no. 3, p. 853.

    Article  CAS  Google Scholar 

  8. Noveron, J.C., Lah, M.S., Del Sesto, R.E., et al., J. Am. Chem. Soc., 2002, vol. 124, p. 6615.

    Article  Google Scholar 

  9. Nemilova, M.Yu., Pautova, A.K., Shvedene, N.V., et al., Abstracts of Papers, XXV Mezhdunar. Chugaevskaya konf. po koordinatsionnoi khimii (XXV International Chugaev Conf. on Coordination Chemistry), Suzdal’, 2011, p. 484.

    Google Scholar 

  10. Nemilova, M.Yu., Shvedene, N.V., Mikhalev, O.V., and Il’ina, I.G., Abstracts of Papers, VIII Vsemir. konf. po elektrokhimicheskim metodam analiza “EMA-2012” (VIII World Conf. on Electrochemical Analysis Methods EMA-2012), Ufa, 2012, p. 110.

    Google Scholar 

  11. Mikhalev, O.V., Nemilova, M.Yu., Shvedene, N.V., and Milaeva, E.R., Abstracts of Papers, XII Vseros. konf. s mezhdunar. uchastiem “Problemy sol’vatatsii i kompleksoobrazovaniya v rastvorakh. Ot effektov v rastvorakh k novym materialam” (XII All-Russia Conf. with International Participation “Problems of Solvation and Complexation in Solutions. From Solution Effects to New Materials”), Ivanovo, 2015, p. 96.

    Google Scholar 

  12. Vrednye khimicheskie veshchestva. Neorganicheskie soedineniya I-IV grupp: sprav. izd. (Hazardous Chemicals. Inorganic Compounds of Group I–IV Elements. A Handbook), Filov, V.A. et al., Eds., Lenigrad: Knimiya, 1988.

  13. Sbornik sanitarno-gigienicheskikh normativov i metodov kontrolya vrednykh veshchestv v ob’ektakh okruzhayushchei sredy (Collection of Sanitary Standards and Methods for the Control of Hazardous Chemicals in the Environment), Moscow, 1991, p. 512.

  14. Cammann, K., Working with Ion Selective Electrodes, Berlin: Springer, 1979.

    Book  Google Scholar 

  15. Hassan, S.M., Abou Galia, M.H., Amr, E., and Ayman, H.K., Anal. Chim. Acta, 2003, vol. 482, p. 9.

    Article  CAS  Google Scholar 

  16. Arvand, M., Zanjanchi, M.A., and Heydari, L., Sens. Actuators, 2007, vol. 122, p. 301.

    Article  CAS  Google Scholar 

  17. Erden, S., Demirel, A., Memon, S., et al., Sens. Actuators, 2006, vol. 113, p. 290.

    Article  CAS  Google Scholar 

  18. Segui, M.J., Lizondo-Sabater, J., and Soto, J., Talanta, 2006, vol. 68, p. 1182.

    Article  CAS  Google Scholar 

  19. Ying, M., Yuan, R., Li, Z., et al., Fresenius J. Anal. Chem., 1998, vol. 361, p. 437.

    Article  CAS  Google Scholar 

  20. Shamsipura, M., Ershada, S., Samadia, N., et al., Talanta, 2005, vol. 65, p. 991.

    Article  Google Scholar 

  21. Shamsipur, M., Khayatian, G., and Tangestaninejad, S., Electroanalysis, 1999, vol. 11, p. 1340.

    Article  CAS  Google Scholar 

  22. Khorasani, J.H., Motaghi, H., Tangenstaninejad, S., and Moghadam, V., Sens. Acuators, B, 2002, vol. 87, p. 448.

    Article  CAS  Google Scholar 

  23. Ardakani, M.M., Sadeghi, A., and Salavati-Niasari, M., Talanta, 2005, vol. 66, p. 837.

    Article  CAS  Google Scholar 

  24. Singh, A.K., Singh, U.P., Mehtab, S., and Aggarwal, V., Sens. Actuators, B, 2007, vol. 125, p. 453.

    Article  CAS  Google Scholar 

  25. Xu, W., Chai, Y., Yuan, R., and Liu, S., Anal. Bioanal. Chem., 2006, vol. 385, p. 926.

    Article  CAS  Google Scholar 

  26. Ardakani, M.M., Salavati-Niassaria, M., and Sadeghia, A., New J. Chem., 2004, vol. 28, p. 595.

    Article  Google Scholar 

  27. Amini, M.K., Rafi, A., Ghaedi, M., et al., Microchem. J., 2003, vol. 75, p. 143.

    Article  CAS  Google Scholar 

  28. Xu, W., Zhang, Y., Chai, Y., and Yuan, R., Desalination, 2009, vol. 249, p. 139.

    Article  CAS  Google Scholar 

  29. Chai, Y., Dai, J., Yuan, R., et al., Desalination, 2005, vol. 80, p. 207.

    Article  Google Scholar 

  30. Yuan, R., Wang, X.L., Xua, L., et al., Electrochem. Commun., 2003, vol. 5, p. 717.

    Article  CAS  Google Scholar 

  31. Amini, M.K., Shahrokhian, S., and Tangenstanijad, S., Anal. Chim. Acta, 1999, vol. 402, p. 137.

    Article  CAS  Google Scholar 

  32. Abbaspour, A., Kamyabi, M.A., Esmaeilbeig, A.R., and Kia, R., Talanta, 2002, vol. 57, p. 859.

    Article  CAS  Google Scholar 

  33. Han, W.S., Hong, T.K., and Lee, Y.H., J. Anal. Chem., 2011, vol. 67, no. 2, p. 731.

    Article  Google Scholar 

  34. Ardakania, M.M., Ensafi, A., Niasaria, M.S., and Chahookia, S.M., Anal. Chim. Acta, 2002, vol. 462, p. 25.

    Article  Google Scholar 

  35. Ardakani, M.M., Jamshidpour, M., Naeimi, H., and Moradi, L., Anal. Sci., 2006, vol. 22, p. 1221.

    Article  CAS  Google Scholar 

  36. Ganjali, M.R., Yousefi, M., Javanbakht, M., et al., Anal. Sci., 2002, vol. 18, p. 887.

    Article  CAS  Google Scholar 

  37. Zamani, H.A., Malekzadegan, F., and Ganjali, M.R., Anal. Chim. Acta, 2006, vol. 555, p. 336.

    Article  CAS  Google Scholar 

  38. Sheldrick, G.M., Acta Crystallogr., Sect C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    M. Yu. Nemilova, N. V. Shvedene, O. V. Mikhalev & D. B. Shpakovsky

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119334, Russia

    I. V. Fedyanin

Authors
  1. M. Yu. Nemilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Shvedene
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Mikhalev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. V. Fedyanin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. B. Shpakovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to M. Yu. Nemilova or O. V. Mikhalev.

Additional information

Original Russian Text © M.Yu. Nemilova, N.V. Shvedene, O.V. Mikhalev, I.V. Fedyanin, D.B. Shpakovsky, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 11, pp. 668–675.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nemilova, M.Y., Shvedene, N.V., Mikhalev, O.V. et al. New metal complex systems as electrode active components of ion selective electrode membranes. Russ J Coord Chem 43, 736–744 (2017). https://doi.org/10.1134/S1070328417110057

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328417110057

Keywords

Search

Navigation