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Synthesis and structure of bis-hexaaquasodium bis-nitrilotris(methylenephosphonato)decaaquamonohydrohexasodiumlanthanate trihydrate [Na(H2O)6]2[LaNa6H(H2O)10{N(CH2PO3)3}2] · 3H2O

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Abstract

A complex salt of nitrilotris(methylenephosphonic acid) with sodium and lanthanum was prepared, isolated, and studied. The salt [Na(H2O)6]2[LaNa6H(H2O)10{N(CH2PO3)3}2] · 3H2O crystallizes in space group P21/c, Z = 2, a = 11.86630(10), b = 10.55060(10), c = 19.99270(10) Å, β = 94.6760°. The La coordination polyhedron is a virtually regular rhombohedron. The Na atom is coordinated at the vertices of a distorted octahedron. Both ligand molecules chelate the La atom; each PO3 group forms a La–O–P–O–Na bridge; the ligand denticity is 7.

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Authors and Affiliations

  1. Lobachevsky National Research University, Nizhny Novgorod, 603950, Russia

    N. V. Somov

  2. Udmurt State University, Izhevsk, 426034, Russia

    F. F. Chausov & R. M. Zakirova

  3. Physical-Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, 426000, Russia

    F. F. Chausov

  4. Institute of Mechanics, Ural Branch, Russian Academy of Sciences, Izhevsk, 426067, Russia

    F. F. Chausov, V. G. Petrov, M. A. Shumilova & V. A. Aleksandrov

Authors
  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. V. G. Petrov
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  5. M. A. Shumilova
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  6. V. A. Aleksandrov
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, V.G. Petrov, M.A. Shumilova, V.A. Aleksandrov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 6, pp. 369–375.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. Synthesis and structure of bis-hexaaquasodium bis-nitrilotris(methylenephosphonato)decaaquamonohydrohexasodiumlanthanate trihydrate [Na(H2O)6]2[LaNa6H(H2O)10{N(CH2PO3)3}2] · 3H2O. Russ J Coord Chem 43, 373–379 (2017). https://doi.org/10.1134/S1070328417060082

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  • DOI: https://doi.org/10.1134/S1070328417060082

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