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Bis(hexaaquasodium) Bis(nitrilo(tris(methylenephosphonato))decaaquamonohydrogenhexasodiumsamarate Hexahydrate [Na(H2O)6]2[SmH{μ7-N(CH2PO3)3}2Na6(H2O)10] · 6H2O: Synthesis, Structure, and Nature of Coordination Bond

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Abstract

A sodium salt of samarium nitrilotris(methylenephosphonate) complex [Na(H2O)6]2[SmH{μ7-N(CH2PO3)3}2Na6(H2O)10] · 6H2O has been synthesized, isolated, and studied. Crystals are monoclinic, space group P21/c, Z = 2, a = 11.8046(2) Å, b = 10.5454(2) Å, c = 19.8116(3) Å, and β = 94.2790(10)°. The Sm atom is coordinated to two acid residues {N(CH2PO3)3} bound to each other through six P–O–Na–O–P bridges. The Sm coordination polyhedron is a rhombohedron elongated along the N–Sm–N axis. The Sm–O bond length (2.379(10) Å) is 0.615(12) Å smaller than Sm–N (2.9944(19) Å), which is explained by back donation of Sm–O bonds and generation of an increased electron density region in the vicinity of the Sm atom.

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Funding

This work was performed in the framework of State Assignment of the Federal Agency of Scientific Organization of the Russian Federation (no. АААА-А17-117022250040-0).

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Authors and Affiliations

  1. Udmurt Federal Research Center, Ural Branch, Russian Academy of Sciences, 426063, Izhevsk, Russia

    F. F. Chausov, N. V. Lomova, M. A. Shumilova, D. K. Zhirov & V. G. Petrov

  2. Lobachevsky State University of Nizhni Novgorod, 603950, Nizhni Novgorod, Russia

    N. V. Somov

  3. Udmurt State University, 426034, Izhevsk, Russia

    R. M. Zakirova

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  1. F. F. Chausov
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Translated by G. Kirakosyan

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Chausov, F.F., Somov, N.V., Lomova, N.V. et al. Bis(hexaaquasodium) Bis(nitrilo(tris(methylenephosphonato))decaaquamonohydrogenhexasodiumsamarate Hexahydrate [Na(H2O)6]2[SmH{μ7-N(CH2PO3)3}2Na6(H2O)10] · 6H2O: Synthesis, Structure, and Nature of Coordination Bond. Russ. J. Inorg. Chem. 65, 854–863 (2020). https://doi.org/10.1134/S0036023620060030

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