Skip to main content
SpringerLink
Log in

Thermal stabilities and crystal structures of two supramolecular microporous frameworks based on carboxylate-dipyridyl mix-ligands

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The mix-ligand system of 5-(4-carboxy-2-nitrophenoxy)isophthalic acid (HСn-H2Ipa) and dipyridyl-type molecule produces two M(II) porous coordination polymers, namely {[Zn(HCn-Ipa)(Dpe)(H2O)] · 2H2O} n (I) and {[Co(Cn-HIpa)(Dpe)(H2O)3] · 2.5H2O} n (II) (Dpe = 1,2-di(4-pyridyl) ethylene). Structure determinations reveal that two complexes feature different one-dimensional (1D) polymers assembling into supramolecular microporous frameworks with different thermal stabilities. The 3D supramolecular frameworks of complex I show relatively lower stability, which can be caused by relatively larger porous cavity absent of the strong hydrogen bonds interaction, whereas thick-layer blocks in complex II are cohered further together by H-bonding interactions to form its 3D supramolecular network with relatively higher stability, indicating extraordinarily stable H-bonding systems; CIF files CCDC nos. 966919 (I) and 966920 (II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Deng, H.X., Grunder, S., Yaghi, O.M., et al., Science, 2012, vol. 336, p. 1018.

    Article  CAS  Google Scholar 

  2. Cui, Y., Yue, Y., Chen, B., et al., Chem. Rev., 2012, vol. 112, p. 1126.

    Article  CAS  Google Scholar 

  3. Chae, H.K., Siberio-Perez, D.Y., Kim, J., et al., Nature, 2004, vol. 427, p. 523.

    Article  CAS  Google Scholar 

  4. Xiang, S.C., He, Y.B., Zhang, Z.J., et al., Nature Commun., 2012, vol. 3, p. 954.

    Article  Google Scholar 

  5. Luo, X.Z., Jia, X.J., Deng, J.H., et al., J. Am. Chem. Soc., 2013, vol. 135, p. 11684.

    Article  CAS  Google Scholar 

  6. Gu, Z.Y., Yang, C.X., Chang, N., et al., Acc. Chem. Res., 2012, vol. 45, p. 734.

    Article  CAS  Google Scholar 

  7. Farrusseng, D., Aguado, S., and Pinel, C., Angew. Chem. Int. Ed., 2009, vol. 48, p. 7502.

    Article  CAS  Google Scholar 

  8. Jiang, H.L. and Xu, Q., Chem. Commun., 2011, vol. 47, p. 3351.

    Article  CAS  Google Scholar 

  9. Jiang, G.Y., Wu, T., Bu, X.H., et al., Cryst. Growth Des., 2011, vol. 11, p. 3713.

    Article  CAS  Google Scholar 

  10. Li, X.L., Liu, G.Z., Wang, L.Y., et al., CrystEngComm, 2012, vol. 14, p. 1729.

    Article  CAS  Google Scholar 

  11. Xin, L.Y., Liu, G.Z., Li, X.L., et al., Russ. J. Coord. Chem., 2013, vol. 39, p. 571.

    Article  CAS  Google Scholar 

  12. Medishetty, R., Lee, S.S., and Vittal, J.J., Inorg. Chem., 2013, vol. 52, p. 2951.

    Article  CAS  Google Scholar 

  13. Li, X.L., Liu, G.Z., Xin, L.Y., et al., Synth. React. Inorg. Met.-Org. Chem., 2015, vol. 45, p. 914.

    Article  CAS  Google Scholar 

  14. Dong, X.Y., Zang, S.Q., Song, Y., et al., J. Am. Chem. Soc., 2013, vol. 135, p. 10214.

    Article  CAS  Google Scholar 

  15. Li, C.P. and Du, M., Chem. Commun., 2011, vol. 47, p. 5958.

    Article  CAS  Google Scholar 

  16. Liu, G.Z., Li, S.H., Wang, L.Y., et al., CrystEngComm, 2013, vol. 15, p. 4571.

    Article  CAS  Google Scholar 

  17. Sheldrick, G.M., A Program for the Siemens Area Detector Absorption Correction, Göttingen Univ. of Göttingen, 1997.

    Google Scholar 

  18. Sheldrick, G.M., SHELXS-97, Program for X-ray Crystal Structure Determination, Göttingen Univ. of Göttingen, 1997.

    Google Scholar 

  19. Sheldrick, G.M., SHELXS-97, Program for X-ray Crystal Structure Refinement, Göttingen Univ. of Göttingen, 1997.

    Google Scholar 

  20. Spek, A.L., PLATON, A Multi-Purpose Crystallographic Tool, Utrecht: Utrecht Univ., 2001.

    Google Scholar 

  21. Ma, L.F., Wang, L.Y., Wang, Y.Y., et al., CrystEng-Comm, 2009, vol. 11, p. 109.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Henan, Luoyang, 471022, P.R. China

    L. Y. Xin, F. Y. Ju, X. L. Li & G. Z. Liu

Authors
  1. L. Y. Xin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Y. Ju
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. X. L. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Z. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Z. Liu.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xin, L.Y., Ju, F.Y., Li, X.L. et al. Thermal stabilities and crystal structures of two supramolecular microporous frameworks based on carboxylate-dipyridyl mix-ligands. Russ J Coord Chem 43, 55–62 (2017). https://doi.org/10.1134/S1070328417010080

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328417010080

Keywords

Search

Navigation