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Synthesis and structure of the rhodium complex [p-Tol4Sb(DMSO-O)] +2 [trans-RhBr4(DMSO-S)2]–[cis-RhBr4(DMSO-S)2]–

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Abstract

The complex [p-(Tol)4Sb(DMSO-O) +2 [trans-RhBr4(DMSO-S)2]–[cis-RhBr4(DMSO-S)2]– (CIF file CCDC no. 1415243) was synthesized by the reaction of sodium hexabromorhodate with tetra(para-tolyl) stibonium bromide in DMSO and studied by X-ray diffraction. The antimony atoms in two types of crystallographically independent [p-Tol4Sb(DMSO-O)]+ cations have a distorted trigonal-bipyramidal coordination with axially arranged DMSO oxygen atoms (Sb–C, 2.088(9)–2.135(10) Å; Sb∙∙∙O, 2.641(10), 2.690(10) Å). In the octahedral [trans-RhBr4(DMSO-S)2]– and [cis-RhBr4(DMSO-S)2]– anions, the dimethyl sulfoxide ligands are coordinated to the metal via the sulfur atoms. The Rh–S distances are longer in the trans-isomer (2.333(2), 2.339(2) Å) than in the cis-isomer (2.303(3), 2.318(4) Å).

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

  2. Lobachevsky State University of Nizhny Novgorod, pr. Gagarina 23, Nizhny Novgorod, 630600, Russia

    N. V. Somov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. N. V. Somov
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, N.V. Somov, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 12, pp. 758–761.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Synthesis and structure of the rhodium complex [p-Tol4Sb(DMSO-O)] +2 [trans-RhBr4(DMSO-S)2]–[cis-RhBr4(DMSO-S)2]– . Russ J Coord Chem 42, 779–782 (2016). https://doi.org/10.1134/S1070328416120058

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  • DOI: https://doi.org/10.1134/S1070328416120058

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