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Synthesis and structure of the rhodium complex [Ph3MeP][RhBr4(DMSO)2-trans]

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Abstract

The ionic complex, methyltriphenylphosphonium(I) trans-bis(dimethylsulfoxido)tetrabromorhodiate, was prepared by the reaction of sodium hexabromorhodiate with methyltriphenylphosphonium bromide in dimethyl sulfoxide and studied by X-ray diffraction. The phosphorus atom in the [Ph3MeP]+ cation has an almost undistorted tetragonal coordination (the CPC angles are 108.3(2)°–110.5(2)°, the P-C bonds are 1.779(6)–1.798(4) Å). In the octahedral complex anion [RhBr4(DMSO)2-trans]−, the dimethyl sulfoxide ligands are coordinated by the sulfur atoms (Rh-S, 2.344(1), 2.336(1); Rh-Br, 2.4839(7)–2.4934(7) Å; SRhS, 179.56(7)°; trans-BrRhBr, 179.30(3)°, 179.56(7)°) (CIF file CCDC no. 978748).

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References

  1. Abbasi, A., Geranmayeh, S., Skripkin, M.Y., and Eriksson, L., Dalton Trans., 2012, vol. 41, p. 850.

    Article  CAS  Google Scholar 

  2. Calligaris, M. and Faleschini, P., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, p. 588.

    Article  Google Scholar 

  3. Gamage, S.N., Morris, R.H., Rettig, S.J., et al., Chem. Commun., 1987, p. 894.

    Google Scholar 

  4. James, B.R., Morris, R.H., Einstein, F.W.B., and Willis, A., Chem. Commun., 1980, p. 31.

    Google Scholar 

  5. Alessio, E., Santi, A.S., Faleschini, P., et al., Dalton Trans., 1994, no. 13, p. 1849.

    Google Scholar 

  6. Gamage, S.N., James, B.R., Rettig, S.J., and Trotter, J., Can. J. Chem., 1988, vol. 66, p. 1123.

    Article  CAS  Google Scholar 

  7. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System, Madison (WI, USA): Bruker AXS Inc., 1998.

  8. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Madison (WI, USA): Bruker AXS Inc., 1998.

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Authors and Affiliations

  1. South Ural State University, pr. Lenina 76, Chelyabinsk, Russia, 454080

    V. V. Sharutin, O. K. Sharutina, V. S. Senchurin & N. V. Somov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. N. V. Somov
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, N.V. Somov, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 11, pp. 683–686.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Synthesis and structure of the rhodium complex [Ph3MeP][RhBr4(DMSO)2-trans]. Russ J Coord Chem 40, 821–824 (2014). https://doi.org/10.1134/S1070328414110074

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  • DOI: https://doi.org/10.1134/S1070328414110074

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