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Synthesis, crystal structure, and luminescent property of a discrete Zn3L3 metallomacrocycle constructed from 5-hydroxyisophthalic acid

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Abstract

An interesting discrete metallomacrocycle (MMC), [Zn3(L)3(H2O)6] · H2O (I), has been prepared by means of self-assembly of Zn(II) salt, 5-hydroxyisophthalic acid (H2L) as organic linker and 5,5’-(pyridine-2,6-diyl)diisophthalic acid (H4L’) as structure-directing agentunder hydrothermal condition. In complex I, the planar trinuclearmetal-organic macrocycles are arranged into 2D sheet layers connected by strong hydrogen bonded between OH groups of the ligands. Then they stack into 3D supramolecular architecture in–ABAB–array way to give a small 1D open channel along the c axis (CIF file CCDC no. 1053024). Additionally, thermal stability and luminescence properties of I were also investigated.

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Authors and Affiliations

  1. Institute of Functional Materials, College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Zigong, 643000, P.R. China

    W. P. Wu, L. Lu, B. Xie, J. Wang & Y. Wu

  2. Department of Architectural Engineering, Sichuan University of Science & Engineering, Zigong, 643000, P.R. China

    Y. Liao

Authors
  1. W. P. Wu
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  2. Y. Liao
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  3. L. Lu
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  4. B. Xie
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  5. J. Wang
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  6. Y. Wu
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Correspondence to W. P. Wu.

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Wu, W.P., Liao, Y., Lu, L. et al. Synthesis, crystal structure, and luminescent property of a discrete Zn3L3 metallomacrocycle constructed from 5-hydroxyisophthalic acid. Russ J Coord Chem 42, 355–359 (2016). https://doi.org/10.1134/S1070328416050092

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  • DOI: https://doi.org/10.1134/S1070328416050092

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