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Synthesis, crystal structure, and luminescent property of two novel Zn/Co(II) coordination polymers with a linear bis-imidazole and dicarboxylate ligands

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Abstract

The linear linker 1,3-bis(2-methylimidazolyl)propane (Bmip) has been used to construct two new coordination polymers with Zn2+ and Co2+ ions and carboxylate donor ligand viz., 4,4’-oxydibenzoic acid (H2Oba). Compounds formed hydrothermally are [Zn(Bmip)(Oba)] n (Ι), [Co(Bmip)(Oba)] n (II). Complexes Ι and II have been characterized by single crystal X-ray diffraction (CIF files CCDC nos. 1033354 (I), 1001813 (II)), IR spectroscopy, thermogravimetry, elemental analysis and powder X-ray diffraction. Single crystal X-ray analysis revealed that complexes Ι and II are isostructural, which exhibit 2D 44-sql net. And the adjacent 44-sql net are further inforced through weak noncovalent C–H···π and H-bonding to form a 3D supramolecular framework. Furthermore, the photoluminescence property of complexes Ι and II in the solid state at room temperature was also investigated.

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Authors and Affiliations

  1. Chemical Engineering College, Shaanxi University of Technology, Hanzhong, 723001, P.R. China

    J. F. Lu, H. G. Ge, J. Shi & X. H. Guo

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  1. J. F. Lu
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  2. H. G. Ge
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  3. J. Shi
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  4. X. H. Guo
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Correspondence to J. F. Lu.

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Lu, J.F., Ge, H.G., Shi, J. et al. Synthesis, crystal structure, and luminescent property of two novel Zn/Co(II) coordination polymers with a linear bis-imidazole and dicarboxylate ligands. Russ J Coord Chem 42, 274–277 (2016). https://doi.org/10.1134/S1070328416030064

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  • DOI: https://doi.org/10.1134/S1070328416030064

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