Abstract
Two new Ln(III) metal-organic frameworks (MOFs) based on 5-nitroisophthalic acid (H2L), namely [Pr4(L)6(H2O)4] n (I) and [Gd(L)(FA)(H2O)2] n (II) (HFA = formic acid), were prepared by solvothermal reactions and structurally characterized by IR, elemental analysis, XRD, and single crystal X-ray diffraction (CIF files CCDC nos. 971379 (I) and 971380 (II)). A 3D {4.62}{410.617.89}{43}2 topology framework of I and a 3D {4.62 2}{42.610.83} topology network of II are constructed respectively with different synthetic conditions. Four kinds of coordination modes are observed for dicarboxylate in these two MOFs in total. Notably, the in situ hydrolysis of DMF solvates leads to the formation of formate ions that was observed in the structure of II. Moreover, the luminescent properties of both complexes and corresponding ligand have been investigated.
Similar content being viewed by others
References
Tian, D., Chen, Q., Li, Y., et al., Angew. Chem. Int. Ed., 2014, vol. 53, p. 837.
Cheng, X.N., Xue, W., Lin, J.B., et al., Chem. Commun., 2010, vol. 46, p. 246.
Du, M., Li, C.P., Chen, M., et al., J. Am. Chem. Soc., 2014, vol. 136, p. 10906.
Li, Y.W., Ma, H., Chen, Y.Q., et al., Cryst. Growth Des., 2012, vol. 12, p. 189.
Sakata, Y., Furukawa, S., Kondo, M., et al., Science, 2013, vol. 339, p. 193.
Gong, H.Y., Rambo, B.M., Karnas, E., et al., J. Am. Chem. Soc., 2011, vol. 133, p. 1526.
Hirai, K., Furukawa, S., Kondo, M., et al., Angew. Chem. Int. Ed., 2011, vol. 50, p. 8057.
Jarikov, V.V. and Kondakov, D.Y., J. Appl. Phys., 2009, vol. 105, p. 034905.
Ghosh, S., Chakrabarty, R., and Mukherjee, P.S., Inorg. Chem., 2009, vol. 48, p. 549.
Terazono, Y., Kodis, G., Liddell, P.A., et al., J. Phys. Chem., B, 2009, vol. 113, p. 7147.
Gao, J.Y., Xiong, X.H., Chen, C.J., et al., Inorg. Chem. Commun., 2013, vol. 31, p. 5.
SAINT, Software Reference Manual, Madison Bruker, AXS, 1998.
Sheldrick, G.M., SADABS, Siemens Area Detector Absorption Corrected Software, Göttingen Univ. of Göttingen, 1996.
Sheldrick, G.M., SHELXTL NT, Version 5. 1, Program for Solution and Refinement of Crystal Structures, Göttingen Univ. of Göttingen, 1997.
Paul, M., Adarsh, N.N., and Dastidar, P., Cryst. Growth Des., 2014, vol. 14.
Zhang, J.P., Zheng, S.L., Huang, X.C., et al., Angew. Chem. Int. Ed., 2004, vol. 43, p. 206.
Wang, D. and Astruc, D., Chem. Rev., 2014, vol. 114, p. 6949.
Xue, Y.S., Jin, F.Y., Zhou, L., et al., Cryst. Growth Des., 2012, vol. 12, p. 6158.
Wang, C., Wang, J.L., and Lin, W., J. Am. Chem. Soc., 2012, vol. 134, p. 19895.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York Wiley, 1986.
Zhang, G., Zhao, X., Dai, F., et al., Inorg. Chem. Commun., 2011, vol. 14, p. 948.
Taylor, J.M., Dawson, K.W., and Shimizu, G.K.H., J. Am. Chem. Soc., 2013, vol. 135, p. 1193.
Meng, Z.R., Zhang, Q.Z., Wu, X.Y., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2006, vol. 62, p. m1033.
Thirumurugan, A. and Natarajan, S., Eur. J. Inorg. Chem., 2004, p. 762.
Liao, L., Ingram, C.W., Vandeveer, D., et al., Inorg. Chim. Acta, 2012, vol. 391, p. 1.
Fu, F., Chen, S.P., Ren, Y.X., et al., Acta Chim. Sin., 2008, vol. 66, p. 1663.
Lin, L., Zhang, X., Zhang, J., et al., J. Mol. Struct., 2011, vol. 1006, p. 83.
Xu, H. and Li, Y., J. Mol. Struct., 2004, vol. 690, p. 137.
Sibille, R., Mazet, T., Malaman, B., et al., Chem. Eur. J., 2012, vol. 18, p. 12970.
Fang, X., Cai, L.M., Shao, Y.C., et al., J. Coord. Chem., 2014, vol. 67, p. 3542.
Carrera, E.I., McCormick, T.M., Kapp, M.J., et al., Inorg. Chem., 2013, vol. 52, p. 13779.
Chang, Z., Zhang, A.S., Hu, T.L., et al., Cryst. Growth Des., 2009, vol. 9, p. 4840.
Allendorf, M.D., Bauer, C.A., Bhakta, R.K., et al., Chem. Soc. Rev., 2009, vol. 38, p. 1330.
Zhou, R.S., Cui, X.B., Song, J.F., et al., J. Solid State Chem., 2008, vol. 181, p. 2099.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Wang, J.J., Zhang, Y.J., Jin, F. et al. Ln(III) metal-organic frameworks with 5-nitroisophthalate ligands: Crystal structures and luminescent properties. Russ J Coord Chem 42, 316–323 (2016). https://doi.org/10.1134/S1070328416050080
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328416050080