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Self assembly of three new copper coordination polymers based on N-[(3-pyridine)-sulfonyl]aspartate: Synthesis and structure

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Abstract

Three new copper coordination polymers [Cu(L) · 6H2O] n (I), [Cu2(L)2] n (II), and [Cu(HL)2] n (III), where H2L is N-[(3-pyridine)-sulfonyl]aspartate, have been synthesized and characterized by singlecrystal X-ray diffraction (CIF files CCDC nos. 1435871 (I), 1435872 (II), 1435873 III), elemental analysis and IR spectra. Moreover, the variable-temperature magnetic susceptibility had been studied for complex I. A structural comparison of these polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for I–III.

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Authors and Affiliations

  1. College of Chemistry and Biological Engineering, Hechi University, Yizhou, 546300, P.R. China

    B. L. Liao & S. X. Li

  2. College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P.R. China

    B. L. Liao, S. X. Li, J. J. Guo, J. J. Jia & Y. M. Jiang

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  1. B. L. Liao
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  2. S. X. Li
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  3. J. J. Guo
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  4. J. J. Jia
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  5. Y. M. Jiang
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Correspondence to Y. M. Jiang.

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Liao, B.L., Li, S.X., Guo, J.J. et al. Self assembly of three new copper coordination polymers based on N-[(3-pyridine)-sulfonyl]aspartate: Synthesis and structure. Russ J Coord Chem 42, 285–291 (2016). https://doi.org/10.1134/S1070328416040035

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  • DOI: https://doi.org/10.1134/S1070328416040035

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