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One-Dimensional Self-assembled Coordination Polymer, {[Cu(bpy)(bpe)(NO3)2]·(H2O)4}n

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Abstract

Coordination polymer {[Cu(bpy)(bpe)(NO3)2]·(H2O)4}n (CP1) has been synthesized using [Cu(bpy)(NO3)2] (where bpy = 2,2′-bipyridine) and bpe (bpe = 1,2-bis(4-pyridyl)ethane as a spacer in equimolar ratio. CP1 was characterized by using Infrared spectroscopy, elemental analysis, and single crystal X-ray diffraction. The crystal structure confirms that the CP1 is formed with a bridging bpe linker giving rise to helical chain in one-dimensional (1D) structure. Copper ion is connected to two nitrogen atoms from bpy, two oxygen atoms from nitrate anions (major component) and two nitrogen atoms from two bpe ligands. There is an additional minor component which is five coordinate. The hydrogen bonding links the helical chains to generate a three dimensional (3D) network structure.

Graphical abstract

A one-dimensional coordination polymer {[(Cu(bpy)(bpe)(NO3)2]·H2O)4}n (CP1) has been synthesized using [Cu(bpy)(NO3)2] (where bpy = 2,2′-bipyridine) as a building block and bpe (bpe = 1,2-bis(4-pyridyl)ethane) as a spacer in a equimolar ratio.

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Acknowledgements

VAK acknowledges the SERB, DST, Government of India (NO. SB/FT/CS-063/2014) for financial support. V.A. Kawade wish to thank Dr. Barnabas R. J. Principal, Ahmednagar College for encouragement and support. We thank SAIF, STIC, Cochin University, Kerala for IR spectrum. We thank SAIF, IIT-Bombay for elemental analysis.

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Authors and Affiliations

  1. Department of Chemistry, Dr. John Barnabas P. G. School for Biological Studies, Ahmednagar College, Ahmednagar, Maharashtra, 414 001, India

    Vitthal A. Kawade

  2. Department of Chemistry, Karnatak University, Dharwad, Karnataka, 580003, India

    Satish S. Bhat

  3. Department of Chemistry, Howard University, Washington, DC, 20059, USA

    Ray J. Butcher

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  1. Vitthal A. Kawade
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  2. Satish S. Bhat
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Correspondence to Vitthal A. Kawade.

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Kawade, V.A., Bhat, S.S. & Butcher, R.J. One-Dimensional Self-assembled Coordination Polymer, {[Cu(bpy)(bpe)(NO3)2]·(H2O)4}n. J Chem Crystallogr 49, 275–280 (2019). https://doi.org/10.1007/s10870-019-00782-9

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