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Aquanitrilotris(methylenephosphonato)bis(dimercury(I)) hydrate, [(Hg2)2(H2O)N(CH2PO3)3H2] · H2O: Synthesis, structure, and properties

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Abstract

A reaction of dimercury(I) dinitrate with nitrilotris(methylenephosphonic acid), N(CH2PO3)3H6, gave the complex [(Hg2)2(H2O){N(CH2PO3)3H2}] · H2O. The crystals of the complex are triclinic, space group \(P\bar 1\), Z = 2, a = 8.3436(3), b = 9.0744(3), c = 11.1124(4) Å, α = 91.875(3)°, β = 104.452(3)°, γ = 92.195(3)° (CIF file CCDC no. 1051860). The atoms of either dimercury cation are coordinated differently, making up a distorted tetrahedron and a distorted trigonal bipyramid. The ligand is coordinated to the Hg atoms through seven donor atoms: six (out of nine) O atoms and a N atom. The coordination involves the formation of chelate rings: two four-membered, three five-membered, a six-membered, and an eight-membered ring (CIF file CCDC no. 1051860).

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Authors and Affiliations

  1. Lobachevsky State University, Nizhny Novgorod, Russia

    N. V. Somov

  2. Physical-Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, Russia

    F. F. Chausov

  3. Udmurt State University, Izhevsk, Russia

    F. F. Chausov & R. M. Zakirova

  4. Institute of Mechanics, Ural Branch, Russian Academy of Sciences, Izhevsk, Russia

    M. A. Shumilova, V. A. Aleksandrov & V. G. Petrov

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  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. M. A. Shumilova
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  5. V. A. Aleksandrov
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  6. V. G. Petrov
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, M.A. Shumilova, V.A. Aleksandrov, V.G. Petrov, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 1, pp. 39–45.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. Aquanitrilotris(methylenephosphonato)bis(dimercury(I)) hydrate, [(Hg2)2(H2O)N(CH2PO3)3H2] · H2O: Synthesis, structure, and properties. Russ J Coord Chem 42, 37–43 (2016). https://doi.org/10.1134/S107032841601005X

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  • DOI: https://doi.org/10.1134/S107032841601005X

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