Abstract
Aqua{pentahydrogennitrilotris(methylenephosphonato)}lithium hydrate is a linear coordination polymer. Its crystal structure is described in space group P –1, Z = 2; a = 5.5732(2), b = 7.0106(2), and c = 16.9010(5) Å; α = 97.515(2)°, β = 94.551(2)°, and γ = 95.123(2)°. The tetrahedral coordination of the Li atom includes two oxygen atoms of a phosphonate ligand, one oxygen atom of another phosphonate ligand, and a water molecule. Complex formation is accompanied by closing of the eight-membered Li–O–P–C–N–C–P–O chelate ring. Polymeric chains run along the [100] direction. The chains are connected by hydrogen bonds.
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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, 2016, published in Kristallografiya, 2016, Vol. 61, No. 3, pp. 400–405.
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Somov, N.V., Chausov, F.F. & Zakirova, R.M. Aqua{pentahydrogennitrilotris(methylenephosphonato)}lithium hydrate [Li(H2O){N(CH2PO3)3H5}] • H2O: Synthesis and structure. Crystallogr. Rep. 61, 395–400 (2016). https://doi.org/10.1134/S1063774516030263
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DOI: https://doi.org/10.1134/S1063774516030263