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Lanthanide complexes with pyridine-2,6-dicarboxylic acid: synthesis, crystal structure, thermal and magnetic properties of [LnPDA)2(PDAH2)] · (DMAH2)2(DMAH0.5)2

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Abstract

Mild solvothermal synthesis, structures, thermal and magnetic properties of coordination complexes [Ln(PDA)2(PDAH2)] · (DMAH2)2(DMAH0.5)2(I–IV) (PDA = pyrdine-2,6-dicarboxylate anion, DMAH = dimethylamine, Ln = Ce, Nd, Sm, and Ho) are described. The DMAH molecules in I–IV, generated in situ from hydrolysis of N,N-dimethylformamide, are responsible to assemble three dimensional coordination polymers through N–H···O and C–H···O hydrogen bonds. Distorted tricapped trigonal prismatic LnO6N3 geometry having 14 triangular faces is attributed to mean deviation of dihedral angles while nitrogen shows fairly triangular faces having dihedral angle close to 60°C (CIF files CCDC nos. 872065 (I), 872070 (II), 872069 (III), and 872066 (IV)). Curie–Weiss law and the overall magnetic behavior are typical for the presence of antiferromagnetic exchange coupling interactions between lanthanide. Thermal decomposition analyses reveal removal of ammonia and resultant complexes showthermal stability. Complexes have been further characterized by using elemental analyzer and FT-IR spectroscopy.

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References

  1. Eddaoudi, M., Kim, J., Rosi, N., et al., Science, 2002, vol. 295, p. 469.

    Article  CAS  Google Scholar 

  2. Allendorf, M.D., Bauer, C.A., Bhakta, R.K., et al., Chem. Soc. Rev., 2009, vol. 38, p. 1330.

    Article  CAS  Google Scholar 

  3. Huang, Y.G., Jiang, F.L., and Hong, M.C., Coord. Chem. Rev., 2009, vol. 253, p. 2814.

    Article  CAS  Google Scholar 

  4. Munakata, M., Ning, G.L., Kuroda-Sowa, T., et al., Inorg. Chem., 1998, vol. 37, p. 5651.

    Article  CAS  Google Scholar 

  5. Losier, P. and Zaworotko, M.J., Angew. Chem. Int. Ed., 1996, vol. 35, p. 2779.

    Article  CAS  Google Scholar 

  6. Wen, L.L., Wang, F.-M., Leng, X.-K., et al., J. Inorg. Organomet. Polym. Mater., 2010, vol. 20, p. 313.

    Article  CAS  Google Scholar 

  7. Gable, R.W., Hoskins, B.F., and Robson, R., J. Chem. Soc., Chem. Commun., 1990, p. 1677.

    Google Scholar 

  8. Desiraju, G.R., Angew. Chem. Int. Ed., 1995, vol. 34, p. 2311.

    Article  CAS  Google Scholar 

  9. Schauer, C.L., Matwey, E., Fowler, F.W., et al., J. Am. Chem. Soc., 1997, vol. 119, p. 10245.

    Article  CAS  Google Scholar 

  10. Crystal Design: Structure and Function, Desiraju, G.R., Ed., New York: Wiley, 2003, p. 4.

  11. Khan, I.U., Sharif, S., and Sahin, O., J. Coord. Chem., 2013, vol. 66, p. 3113.

    Article  CAS  Google Scholar 

  12. Sharif, S., Khan, I.U., Sahin, O., et al., J. Inorg. Organomet., 2012, vol. 22, p. 1165.

    Article  CAS  Google Scholar 

  13. Macgillivray, L.R., Metal-Organic Frameworks Design and Application, Hoboken (NJ, USA): Wiley, 2010, p. 13.

    Book  Google Scholar 

  14. Feng, M.-L., Xie, Z.-L., and Huang, X.-Y., Inorg. Chem., 2009, vol. 48, p. 3904.

    Article  CAS  Google Scholar 

  15. Feng, M.L., Kong, D.N., Xie, Z.L., et al., Angew. Chem., Int. Ed., 2008, vol. 47, p. 8623.

    Article  CAS  Google Scholar 

  16. Zhou, Y.-X., Cheng, G.-X., Wuc, B.-L., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2007, vol. 63, p. m2285.

    Article  Google Scholar 

  17. Xu, Y.L., Han, Z., Lin, Z., et al., Eur. J. Inorg. Chem., 2004, p. 4457.

    Google Scholar 

  18. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  19. Betteridge, P.W., Carruthers, J.R., Cooper, R.I., et al., J. Appl. Cryst., 2003, vol. 36, p. 1487.

    Article  CAS  Google Scholar 

  20. Farrugia, L.J., J. Appl. Cryst., 1999, vol. 32, p. 837.

    Article  CAS  Google Scholar 

  21. Macrae, C.F., Bruno, I.J., Chisholm, J.A., et al., J. Appl. Cryst., 2008, vol. 41, p. 466.

    Article  CAS  Google Scholar 

  22. Spek, A.L., J. Appl. Crystallogr., 2003, vol. 26, p. 1.

    Google Scholar 

  23. Crystal and Molecular Structures Program for Mac and Windows, CrystalMaker® software, www.crystalmaker.com

  24. OriginPro 8 SRO, v. 8.0724 (B724), Northampton (MA, USA), www.originLab.com

  25. Blundell, S. and Thouless, D., Magnetism in Condensed Matter, Oxford: Oxford Univ., 2001.

    Google Scholar 

  26. Want, B., Ahmad, F., and Kotru, P.N., J. Alloys Compd., 2008, vol. 448, p. L5.

  27. Prasad, T.K. and Rajasekharan, M.V., Cryst. Growth Des., 2008, vol. 8, p. 1346.

    Article  CAS  Google Scholar 

  28. Wang, H.S., Zhao, B., Zhai, B., et al., Cryst Growth Des., 2007, vol. 7 p. 1851.

    Article  CAS  Google Scholar 

  29. Gao, H.L., Zhao, B., Zhao, X.Q., et al., Inorg. Chem., 2008, vol. 47, p. 11057.

    Article  CAS  Google Scholar 

  30. Karroker, D.G., J. Chem. Ed., 1970, vol. 47, p. 424.

    Article  Google Scholar 

  31. Keller, R.N., J. Chem. Ed., 1951, p. 312.

    Google Scholar 

  32. Rare Earth Coordination Chemistry Fundamentals and Applications, Huang, C., Ed., Wiley (Asia), 2010, p. 47.

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Authors and Affiliations

  1. Department of Chemistry, Lahore College for Women University, Lahore, 54000, Jail Road Lahore, Pakistan

    S. Sharif & B. Khan

  2. Sinop University, Scientific and Technological Research Application and Research Center, 57010, Sinop, Turkey

    O. Şahin

  3. Department of Chemistry, GC Pakistan University, Materials Chemistry Laboratory, 54000, Lahore, Pakistan

    I. U. Khan

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  1. S. Sharif
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  2. B. Khan
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  3. O. Şahin
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  4. I. U. Khan
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Correspondence to S. Sharif.

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Sharif, S., Khan, B., Şahin, O. et al. Lanthanide complexes with pyridine-2,6-dicarboxylic acid: synthesis, crystal structure, thermal and magnetic properties of [LnPDA)2(PDAH2)] · (DMAH2)2(DMAH0.5)2 . Russ J Coord Chem 42, 56–65 (2016). https://doi.org/10.1134/S1070328416010048

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  • DOI: https://doi.org/10.1134/S1070328416010048

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