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Syntheses, luminescence, and hirshfeld surface analyses of three lanthanide coordination polymers directed by flexible carboxylate ligand

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Abstract

Three new complexes, namely {[Ln(L)3(2,2'-Bipy)] n · 2H2O} (Ln = Pr (I), Sm (II) and Nd (III)) (HL = 3-(4-hydroxyphenyl)propanoic acid), have been synthesized and structurally characterized by single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1045041 (I), 1045042 (II), 1045043 (III)). The structural determination revealed that I–III have similar dinuclear motifs, which can be further linked into 1D chain via the hydrogen bond interactions. Furthermore, the luminescent properties of I–III show the strong emissive power and feature.

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Authors and Affiliations

  1. School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zigong, 643000, P.R. China

    L. Lu, J. Wang, W. P. Wu, B. Xie & Y. Wu

  2. Guangdong Medical College, School of Pharmacy, Dongguan, 523808, P.R. China

    A. Q. Ma

  3. Department of Chemistry, Faculty of Science, University of Lucknow, Lucknow, 226007, India

    A. Kumar

Authors
  1. L. Lu
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  2. J. Wang
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  3. A. Q. Ma
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  4. W. P. Wu
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  5. B. Xie
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  6. Y. Wu
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  7. A. Kumar
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Corresponding authors

Correspondence to L. Lu, A. Q. Ma or A. Kumar.

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Lu, L., Wang, J., Ma, A.Q. et al. Syntheses, luminescence, and hirshfeld surface analyses of three lanthanide coordination polymers directed by flexible carboxylate ligand. Russ J Coord Chem 41, 673–680 (2015). https://doi.org/10.1134/S107032841510005X

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  • DOI: https://doi.org/10.1134/S107032841510005X

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