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A hetero trinuclear manganese(III)-iron(II) complex derived from N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane: Synthesis, crystal structure, and antimicrobial activity

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Abstract

A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(ClSalen)(H2O)]2[Fe(CN)5(NO)] · CH3OH · H2O, where ClSalen is the dianionic form of N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination (CIF file CCDC no. 1024666). The crystal of the complex is orthorhombic: space group Pca21, a = 27.784(2), b = 10.8876(6), c = 15.1755(8) Å, V = 4590.5(4) Å3, Z = 2, R 1 = 0.0596, wR 2 = 0.1406. The bis-Schiff base ligand coordinates to the Mn atom through two phenolate O and two imine N atoms. Each Mn atom in the complex is in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligand, and with the axial donor atoms come from a water O atom and a cyanide N atom. The effects of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan Henan, 467000, P.R. China

    X. M. Hu, L. W. Xue, G. Q. Zhao & W. C. Yang

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  1. X. M. Hu
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  2. L. W. Xue
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  3. G. Q. Zhao
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  4. W. C. Yang
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Correspondence to L. W. Xue.

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Hu, X.M., Xue, L.W., Zhao, G.Q. et al. A hetero trinuclear manganese(III)-iron(II) complex derived from N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane: Synthesis, crystal structure, and antimicrobial activity. Russ J Coord Chem 41, 537–542 (2015). https://doi.org/10.1134/S1070328415080011

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  • DOI: https://doi.org/10.1134/S1070328415080011

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