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Yttrium(III) and lanthanum(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and study by mass spectrometry, X-ray diffraction analysis, and 89Y and 139La NMR spectroscopy

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Abstract

The reactions of LaCl3 and YCl3 with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dione (HL) and 1,10-phenanthroline (Phen) in the presence of a base afford complexes [La(L)3(Phen)] (I) and [Y(L)3(Phen)] (II). Unstable solvates I · iso-PrOH (III) and II · iso-PrOH (IV) are obtained from solutions of the complexes in 2-propanol, and their structures are determined by X-ray diffraction analysis (CIF files CCDC 1026802 (III) and 1026808 (IV)). The compositions of the complexes are additionally studied by 1H, 13C, 89Y, and 139La NMR methods. Fragmentation is studied by laser desorption/ionization (LDI) and electrospray ionization (ESI) mass spectrometry.

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Authors and Affiliations

  1. Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991, Russia

    I. V. Taidakov, N. P. Datskevich & A. G. Vitukhnovskii

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia

    Yu. A. Strelenko

  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119992, Russia

    R. S. Borisov

  4. Kuban State University, ul. Karla Libknekhta 9, Krasnodar, 350640, Russia

    A. Z. Temerdashev

Authors
  1. I. V. Taidakov
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  2. Yu. A. Strelenko
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  3. R. S. Borisov
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  4. A. Z. Temerdashev
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  5. N. P. Datskevich
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  6. A. G. Vitukhnovskii
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Correspondence to I. V. Taidakov.

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Original Russian Text © I.V. Taidakov, Yu.A. Strelenko, R.S. Borisov, A.Z. Temerdashev, N.P. Datskevich, A.G. Vitukhnovskii, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 4, pp. 203–212.

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Taidakov, I.V., Strelenko, Y.A., Borisov, R.S. et al. Yttrium(III) and lanthanum(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and study by mass spectrometry, X-ray diffraction analysis, and 89Y and 139La NMR spectroscopy. Russ J Coord Chem 41, 230–239 (2015). https://doi.org/10.1134/S1070328415040089

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  • DOI: https://doi.org/10.1134/S1070328415040089

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