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Yttrium complexes with 3,6-bis(tert-butylcatecholate)

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Abstract

Heterometallic complex [K3Y(Cat36)3(Dme)4] (I) or binuclear complex [Y2(Cat36)3(Dme)3] · Dme (II · Dme) is synthesized, depending on the reactant ratio, by the reaction of YCl3 with 3,6-bis(tertbutylcatecholate) potassium salt (K2Cat36) in 1,2-dimethoxyethane (Dme). Both complexes are characterized by single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1527929 (I) and 1527930 (II)) and 1H and 13C NMR spectroscopy.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    P. A. Petrov & D. G. Samsonenko

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    P. A. Petrov & D. G. Samsonenko

Authors
  1. P. A. Petrov
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  2. D. G. Samsonenko
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Correspondence to P. A. Petrov.

Additional information

Original Russian Text © P.A. Petrov, D.G. Samsonenko, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 8, pp. 460–464.

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Petrov, P.A., Samsonenko, D.G. Yttrium complexes with 3,6-bis(tert-butylcatecholate). Russ J Coord Chem 43, 500–504 (2017). https://doi.org/10.1134/S1070328417080048

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  • DOI: https://doi.org/10.1134/S1070328417080048

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